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Gadolinium(III) nitrate





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Gadolinium(III) nitrate is an inorganic compound of gadolinium. This salt is used as a water-soluble neutron poisoninnuclear reactors.[1] Gadolinium nitrate, like all nitrate salts, is an oxidizing agent.

Gadolinium(III) nitrate
Identifiers

CAS Number

3D model (JSmol)

ChemSpider
ECHA InfoCard 100.030.385 Edit this at Wikidata

PubChem CID

CompTox Dashboard (EPA)

  • InChI=1S/Gd.3NO3/c;3*2-1(3)4/q+3;3*-1 checkY

    Key: MWFSXYMZCVAQCC-UHFFFAOYSA-N checkY

  • InChI=1/Gd.3NO3/c;3*2-1(3)4/q+3;3*-1

    Key: MWFSXYMZCVAQCC-UHFFFAOYAX

  • [Gd+3].O=[N+]([O-])[O-].[O-][N+]([O-])=O.[O-][N+]([O-])=O

Properties

Chemical formula

Gd(NO3)3
Molar mass 343.26 g/mol
Appearance White crystalline solid
Density 2.3 g/cm3
Melting point 91 °C (196 °F; 364 K)

Solubility in water

Soluble
Hazards
Safety data sheet (SDS) External MSDS

Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

checkY verify (what is checkY☒N ?)

Infobox references

The most common form of this substance is hexahydrate Gd(NO3)3•6H2O with molecular weight 451.36 g/mol and CAS Number: 19598-90-4.[1]

Use

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Gadolinium nitrate was used at the Savannah River Site heavy water nuclear reactors and had to be separated from the heavy water for storage or reuse.[2][3] The Canadian CANDU reactor, a pressurized heavy water reactor, also uses gadolinium nitrate as a water-soluble neutron poison in heavy water.

Gadolinium nitrate is also used as a raw material in the production of other gadolinium compounds, for production of specialty glasses and ceramics and as a phosphor.

References

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  1. ^ DOE Fundamentals Handbook: Nuclear Physics and Reactor Theory (PDF). U.S. Department of Energy. January 1993. p. 31. Archived from the original (PDF) on 2008-04-23. Retrieved 2007-09-26.
  • ^ E. Wilde; C. Berry. "Novel Method for Removing Gadolinium from Used Heavy Water Reactor Moderator".
  • ^ E.W. Wilde; M.B. Goli; C.J. Berry; J.W. Santo Domingo; H.L. Martin. "Novel Method for Removing Gadolinium from Used Heavy Water Reactor Moderator" (PDF).

  • Retrieved from "https://en.wikipedia.org/w/index.php?title=Gadolinium(III)_nitrate&oldid=1178970792"
     



    Last edited on 7 October 2023, at 01:08  





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    This page was last edited on 7 October 2023, at 01:08 (UTC).

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