Potassium carbonate

Potassium carbonate is the primary component of potash and the more refined pearl ash or salts of tartar. Historically, pearl ash was created by baking potash in a kiln to remove impurities. The fine, white powder remaining was the pearl ash. The first patent issued by the US Patent Office was awarded to Samuel Hopkins in 1790 for an improved method of making potash and pearl ash.^[5]

In late 18th-century North America, before the development of baking powder, pearl ash was used as a leavening agent for quick breads.^[6][7]

The modern commercial production of potassium carbonate is by reaction of potassium hydroxide with carbon dioxide:^[3]

2 KOH + CO₂ → K₂CO₃ + H₂O

From the solution crystallizes the sesquihydrateK₂CO₃·3⁄2H₂O ("potash hydrate"). Heating this solid above 200 °C (392 °F) gives the anhydrous salt. In an alternative method, potassium chloride is treated with carbon dioxide in the presence of an organic amine to give potassium bicarbonate, which is then calcined:

2 KHCO₃ → K₂CO₃ + H₂O + CO₂

• (historically) for soap, glass, and dishware production
• as a mild drying agent where other drying agents, such as calcium chloride and magnesium sulfate, may be incompatible. It is not suitable for acidic compounds, but can be useful for drying an organic phase if one has a small amount of acidic impurity. It may also be used to dry some ketones, alcohols, and amines prior to distillation.^[8]
• incuisine, where it has many traditional uses. It is used in some types of Chinese noodles and mooncakes, as well as Asian grass jelly and Japanese ramen. German gingerbread recipes often use potassium carbonate as a baking agent, although in combination with hartshorn.
• in the alkalizationofcocoa powder to produce Dutch process chocolate by balancing the pH (i.e., reduce the acidity) of natural cocoa beans; it also enhances aroma. The process of adding potassium carbonate to cocoa powder is usually called "Dutching" (and the products referred to as Dutch-processed cocoa powder), as the process was first developed in 1828 by Dutchman Coenraad Johannes van Houten.
• as a buffering agent in the production of meadorwine.
• in antique documents, it is reported to have been used to soften hard water.^[9]
• as a fire suppressant in extinguishing deep-fat fryers and various other B class-related fires.
• incondensed aerosol fire suppression, although as the byproduct of potassium nitrate.
• as an ingredient in welding fluxes, and in the flux coating on arc-welding rods.
• as an animal feed ingredient to satisfy the potassium requirementsoffarmed animals such as broiler breeder chickens.
• as an acidity regulator in Swedish snus snuff tobacco

• A Dictionary of Science, Oxford University Press, New York, 2004
• Yu. Platonov, Andrew; Evdokimov, Andrey; Kurzin, Alexander; D. Maiyorova, Helen (29 June 2002). "Solubility of Potassium Carbonate and Potassium Hydrocarbonate in Methanol". Journal of Chemical & Engineering Data. 47 (5): 1175–1176. doi:10.1021/je020012v.

• International Chemical Safety Card 1588