The knockout stages of the Copa Libertadores 2007 tournament were played on a home and away basis. The aggregate score determines the team advancing to the next round, with the away goals rule and a penalty shootoutastiebreakers, in that order. No extra time is played.
The teams have been seeded 1 to 8 (first placed teams from group stage) and 9 to 16 (second placed teams from each group) and the ties will be 1 vs 16, 2 vs 15, etc.
| Teams qualified as first place | Teams qualified as second place |
| Seed | Team | Points | GD | Group |
|---|---|---|---|---|
| 1 |  Santos |
18 | +11 | 8 |
| 2 | Flamengo |
16 | +6 | 5 |
| 3 |  Libertad |
13 | +5 | 1 |
| 4 |  Toluca |
12 | +4 | 7 |
| 5 | Necaxa |
12 | +2 | 2 |
| 6 |  Vélez |
11 | +3 | 4 |
| 7 | Grêmio |
10 | 0 | 3 |
| 8 |  Colo-Colo |
9 | +5 | 6 |
| 9 | América |
12 | +2 | 1 |
| 10 | São Paulo |
11 | +7 | 2 |
| 11 | Boca Juniors |
10 | +6 | 7 |
| 12 |  Nacional |
10 | +4 | 4 |
| 13 |  Cúcuta Deportivo |
9 | +2 | 3 |
| 14 | Paraná |
9 | +1 | 5 |
| 15 | Defensor Sporting |
9 | +1 | 8 |
| 16 |  Caracas |
9 | -3 | 6 |
| Round of 16 | Quarterfinals | Semifinals | Final | ||||||||||||||||||||||||
| 1 | Santos
| 2 | 3 | 5 | |||||||||||||||||||||||
| 16 | Caracas
| 2 | 2 | 4 | |||||||||||||||||||||||
| 1 | Santos
| 0 | 2 | 2 | |||||||||||||||||||||||
| 9 | América
| 0 | 1 | 1 | |||||||||||||||||||||||
| 8 | Colo-Colo
| 0 | 2 | 2 | |||||||||||||||||||||||
| 9 | América
| 3 | 1 | 4 | |||||||||||||||||||||||
| 1 | Santos
| 0 | 3 | 3 | |||||||||||||||||||||||
| 7 | Grêmio (*) (a)
| 2 | 1 | 3 | |||||||||||||||||||||||
| 7 | Grêmio
| 0 | 2 | 2 | |||||||||||||||||||||||
| 10 | São Paulo
| 1 | 0 | 1 | |||||||||||||||||||||||
| 7 | Grêmio
| 0 | 2 | 2 (4) | |||||||||||||||||||||||
| 15 | Defensor
| 2 | 0 | 2 (2) | |||||||||||||||||||||||
| 2 | Flamengo
| 0 | 2 | 2 | |||||||||||||||||||||||
| 15 | Defensor
| 3 | 0 | 3 | |||||||||||||||||||||||
| 7 | Grêmio
| 0 | 0 | 0 | |||||||||||||||||||||||
| 11 | Boca Juniors
| 3 | 2 | 5 | |||||||||||||||||||||||
| 3 | Libertad
| 2 | 1 | 3 | |||||||||||||||||||||||
| 14 | Paraná Clube
| 1 | 1 | 2 | |||||||||||||||||||||||
| 3 | Libertad
| 1 | 0 | 1 | |||||||||||||||||||||||
| 11 | Boca Juniors
| 1 | 2 | 3 | |||||||||||||||||||||||
| 6 | Vélez Sarsfield
| 0 | 3 | 3 | |||||||||||||||||||||||
| 11 | Boca Juniors
| 3 | 1 | 4 | |||||||||||||||||||||||
| 11 | Boca Juniors
| 1 | 3 | 4 | |||||||||||||||||||||||
| 13 | Cúcuta Deportivo
| 3 | 0 | 3 | |||||||||||||||||||||||
| 5 | Necaxa
| 2 | 0 | 2 | |||||||||||||||||||||||
| 12 | Nacional
| 3 | 1 | 4 | |||||||||||||||||||||||
| 12 | Nacional
| 0 | 2 | 2 | |||||||||||||||||||||||
| 13 | Cúcuta Deportivo
| 2 | 2 | 4 | |||||||||||||||||||||||
| 4 | Toluca
| 1 | 2 | 3 | |||||||||||||||||||||||
| 13 | Cúcuta Deportivo
| 5 | 0 | 5 | |||||||||||||||||||||||
(*) To prevent a final with two teams from the same country CONMEBOL has paired Santos FC with Grêmio in the Semi-Finals.[1]
| Caracas FC | 2 – 2 | Santos FC |
|---|---|---|
| Velásquez 55' Vielma 85' |
(Report) | Zé Roberto 15' Kléber 64' |
Attendance: 24,000
Referee: Reinoso 
| América | 3 – 0 | Colo-Colo |
|---|---|---|
| Cabañas 26' Fernández 29' Rojas 53' |
(Report) |
Attendance: 47,307
Referee: Arias
| Defensor | 3 – 0 | Flamengo |
|---|---|---|
| Navarro 5', 75' González 49' |
(Report) |
Attendance: 15,000
Referee: Chandía
| São Paulo FC | 1 – 0 | Grêmio |
|---|---|---|
| Miranda 57' | (Report) |
Attendance: 73,473
Referee: Tardelli
| Boca Juniors | 3 – 0 | Vélez Sársfield |
|---|---|---|
| Riquelme 9' Palermo 61' Rodríguez 89' |
(Report) |
Attendance: 50,000
Referee: Baldassi
| Paraná Clube | 1 – 2 | Libertad |
|---|---|---|
| Josiel 50' | (Report) | Marín 70' Barone 89' |
Attendance: 12,393
Referee: Silvera
| Nacional | 3 – 2 | Necaxa |
|---|---|---|
| Vera 7' Godín 23' Martínez 55' |
(Report) | Kléber 9', 53' |
Attendance: 18,204
Referee: Fagundes
| Cúcuta Deportivo | 5 – 1 | CD Toluca |
|---|---|---|
| Martínez 32', 43', 45' Castro 34' Del Castillo 89' |
(Report) | Sanchéz 1' |
Attendance: 36,304
Referee: Laverni
| Colo-Colo | 2 – 1 | América |
|---|---|---|
| Castro (OG) 70' Suazo 88' |
(Report) | Infante 86' |
Attendance: 26,569
Referee: Larrionda
| CD Toluca | 2 – 0 | Cúcuta Deportivo |
|---|---|---|
| Zinha 21' Scocco 90' |
(Report) |
Attendance: 26,557
Referee: Andarcia
| Vélez Sársfield | 3 – 1 | Boca Juniors |
|---|---|---|
| Zárate 14', 36' Ocampo 80' |
(Report) | Bustos (OG) 32' |
Attendance: 40,232
Referee: Laverni
| Flamengo | 2 – 0 | Defensor |
|---|---|---|
| Renato 36', 47' | (Report) |
Attendance: 67,367
Referee: Baldassi
| Grêmio | 2 – 0 | São Paulo FC |
|---|---|---|
| Tcheco 17' Diego Souza 74' |
(Report) |
Attendance: 46,350
Referee: Chandia
| Santos FC | 3 – 2 | Caracas FC |
|---|---|---|
| Adaílton 34' Zé Roberto 40', 66' |
(Report) | Rey 23' Carpintero 30' |
Attendance: 14,826
Referee: Amarilla
| Libertad | 1 – 1 | Paraná Clube |
|---|---|---|
| Gamarra 84' | (Report) | Joelson 12' |
Attendance: 11,554
Referee: Selman
| Necaxa | 0 – 1 | Nacional |
|---|---|---|
| (Report) | Martínez 88' |
Attendance: 31,314
Referee: Pezzotta
| Cúcuta Deportivo | 2 – 0 | Nacional |
|---|---|---|
| Torres 74' Pérez 89' |
(Report) |
Attendance: 42,400
Referee: Simon
| Defensor | 2 – 0 | Grêmio |
|---|---|---|
| Sorondo 1' Martínez 43' |
(Report) |
Attendance: 38,468
Referee: Selman
| América | 0 – 0 | Santos FC |
|---|---|---|
| (Report) |
Attendance: 100,000
Referee: Silvera
| Boca Juniors | 1 – 1 | Libertad |
|---|---|---|
| Palermo 90' | (Report) | Martínez 81' |
Attendance: 51,397
Referee: Ruiz
| Nacional | 2 – 2 | Cúcuta Deportivo |
|---|---|---|
| Castro 12' Vera 85' |
(Report) | Bustos 22' Pajoy 90' |
Attendance: 20,000
Referee: Pezzotta
| Grêmio | 2 – 0 | Defensor |
|---|---|---|
Tcheco  22' Teco 45' |
(Report) | |
| Penalties | ||
Patrício  Lúcio Douglas Costa Ramón |
4 – 2 |  Fadeuille Peinado de Souza Pereira |
Attendance: 42,387
Referee: Amarilla
| Santos FC | 2 – 1 | América |
|---|---|---|
| Jonas 65' Souto 71' |
(Report) | Bilos 32' |
Attendance: 19,925
Referee: Ruiz
| Libertad | 0 – 2 | Boca Juniors |
|---|---|---|
| (Report) | Riquelme 61' Palacio 71' |
Attendance: 38,000
Referee: Chandia
| Grêmio | 2 – 0 | Santos FC |
|---|---|---|
| Tcheco 34' Carlos Eduardo 36' |
(Report) |
Attendance: 46,123
Referee: Pezzotta
| Cúcuta Deportivo | 3 – 1 | Boca Juniors |
|---|---|---|
| Pérez 40', 65' Bustos 84' |
(Report) | Ledesma 27' |
Attendance: 42,000
Referee: Amarilla
| Santos FC | 3 – 1 | Grêmio |
|---|---|---|
| Renatinho 45', 61' Zé Roberto 76' |
(Report) | Souza 34' |
Attendance: 19,788
Referee: Torres
| Boca Juniors | 3 – 0 | Cúcuta Deportivo |
|---|---|---|
| Riquelme 44' Palermo 60' Battaglia 84' |
(Report) |
Attendance: 50,653
Referee: Silvera
| Boca Juniors | 3 – 0 | Grêmio |
|---|---|---|
| Palacio 18' Riquelme 73' Patrício (OG) 89' |
(Report) |
Attendance: 50,993
Referee: Larrionda
| Grêmio | 0 – 2 | Boca Juniors |
|---|---|---|
| (Report) | Riquelme 69', 81' |
Attendance: 51,851
Referee: Ruiz
| Copa Libertadores 2007 Winners |
|---|
 Club Atlético Boca Juniors Sixth Title |
