| Picture | Name | Father | Birth | Marriage | Became Duchess | Ceased to be Duchess | Death | Spouse |
|---|---|---|---|---|---|---|---|---|
|
Maria de Brignole-Sale [1][2] |
Antoine de Brignole-Sale (Brignole-Sale) |
1812 | 1828 | 1837 2nd Creation |
23 November 1876 husband's death |
9 December 1888 | Raffaele de Ferrari |
| Picture | Name | Father | Birth | Marriage | Became Duchess | Ceased to be Duchess | Death | Spouse |
|---|---|---|---|---|---|---|---|---|
|
Luisa Fernanda of Spain [3] |
Ferdinand VII of Spain (Bourbon) |
30 January 1832 | 10 October 1846 | 9 December 1888 husband's accession |
4 February 1890 husband's death |
2 February 1897 | Prince Antoine |
|
Eulalia of Spain | Francis, Duke of Cádiz (Bourbon) |
12 February 1864 | 6 March 1886 | 4 February 1890 husband's accession |
24 December 1930 husband's death |
8 March 1958 | Infante Antonio |
|
Beatrice of Saxe-Coburg and Gotha | Alfred, Duke of Saxe-Coburg and Gotha (Saxe-Coburg and Gotha) |
20 April 1884 | 15 July 1909 | 24 December 1930 husband's accession |
14 July 1937 husband's abdication |
13 July 1966 | Infante Alfonso |
|
Carla Parodi-Delfino | Leopoldo Girolamo Parodi-Delfino, Senator of the Kingdom of Italy | 13 December 1909 | 10 July 1937 | 14 July 1937 husband's accession |
22 August 1997 husband's death |
27 July 2000 | Infante Alvaro |
|
Véronique Goeders | Jean-Marie Goeders | 16 November 1970 | 28 March 1994 | 22 August 1997 husband's accession |
2001 divorce |
living | Don Alfonso |
| VACANT | ||||||||