Home  

Random  

Nearby  



Log in  



Settings  



Donate  



About Wikipedia  

Disclaimers  



Wikipedia





Ester pyrolysis





Article  

Talk  



Language  

Watch  

Edit  





Ester pyrolysisinorganic chemistry is a vacuum pyrolysis reaction converting esters containing a β-hydrogen atom into the corresponding carboxylic acid and the alkene. The reaction is an Ei elimination and operates in a syn fashion.

Examples include the synthesis of acrylic acid from ethyl acrylate at 590 °C,[1] the synthesis of 1,4-pentadiene from 1,5-pentanediol diacetate at 575 °C [2] or the construction of a cyclobutene framework at 700 °C [3]

An example of ester pyrolosis. Ethyl acrylate decomposes into acrylic acid and ethene (ethylene) gas at 590°C.

References

edit
  1. ^ Organic Syntheses, Coll. Vol. 3, p.30 (1955); Vol. 29, p.2 (1949). Link
  • ^ Organic Syntheses, Coll. Vol. 4, p.746 (1963); Vol. 38, p.78 (1958). Link
  • ^ Organic Syntheses, Coll. Vol. 5, p.235 (1973); Vol. 43, p.17 (1963). Link

  • Retrieved from "https://en.wikipedia.org/w/index.php?title=Ester_pyrolysis&oldid=909647435"
     



    Last edited on 6 August 2019, at 18:29  





    Languages

     


    العربية
    Deutsch
    Español
    فارسی
    Français
    ி

     

    Wikipedia


    This page was last edited on 6 August 2019, at 18:29 (UTC).

    Content is available under CC BY-SA 4.0 unless otherwise noted.



    Privacy policy

    About Wikipedia

    Disclaimers

    Contact Wikipedia

    Code of Conduct

    Developers

    Statistics

    Cookie statement

    Terms of Use

    Desktop