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Isopropyl iodide





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Isopropyl iodide is the organoiodine compound with the formula (CH3)2CHI. It is colorless, flammable, and volatile. Organic iodides are light-sensitive and take on a yellow colour upon storage, owing to the formation of iodine.

Isopropyl iodide
Skeletal formula of isopropyl iodide
Spacefill model of isopropyl iodide
Names
Preferred IUPAC name

2-Iodopropane[1]

Identifiers

CAS Number

3D model (JSmol)

Beilstein Reference

1098244
ChemSpider
ECHA InfoCard 100.000.782 Edit this at Wikidata
EC Number
  • 200-859-3
MeSH isopropyl+iodide

PubChem CID

RTECS number
  • TZ4200000
UNII
UN number 2392

CompTox Dashboard (EPA)

  • InChI=1S/C3H7I/c1-3(2)4/h3H,1-2H3 ☒N

    Key: FMKOJHQHASLBPH-UHFFFAOYSA-N checkY

  • CC(C)I

Properties

Chemical formula

C3H7I
Molar mass 169.993 g·mol−1
Appearance Colourless liquid
Density 1.703 g mL−1
Melting point −90.00 °C; −130.00 °F; 183.15 K
Boiling point 88.8 to 89.8 °C; 191.7 to 193.5 °F; 361.9 to 362.9 K

Solubility in water

1.4 g L−1 (at 12.5 °C)
Solubilityinchloroform Miscible
Solubilityinethanol Miscible
Solubilityindiethyl ether Miscible
Solubilityinbenzene Miscible

Henry's law
constant
 (kH)

890 nmol Pa−1kg−1

Refractive index (nD)

1.4997
Viscosity 6.971 mPa (at 20 °C)
Thermochemistry

Heat capacity (C)

137.3 J K−1 mol−1

Std enthalpy of
formation
fH298)

−77.2–−72.6 kJ mol−1
Hazards
GHS labelling:

Pictograms

GHS02: Flammable GHS07: Exclamation mark

Signal word

Warning

Hazard statements

H226, H302
Flash point 42 °C (108 °F; 315 K)
Related compounds

Related alkanes

  • Ethyl iodide
  • Propane
  • n-Propyl iodide
  • Butane
  • Butyl iodide
  • Related compounds

    Diiodohydroxypropane

    Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

    ☒N verify (what is checkY☒N ?)

    Infobox references

    Preparation

    edit

    Isopropyl iodide is prepared by iodination of isopropyl alcohol using hydrogen iodide or, equivalently, with a mixture of glycerol, iodine, and phosphorus.[2] An alternative preparation involves the reaction of 2-propyl bromide with an acetone solution of sodium iodide (Finkelstein reaction):[3]

    (CH3)2CHBr + NaI → (CH3)2CHI + NaBr

    References

    edit
    1. ^ "isopropyl iodide - Compound Summary". PubChem Compound. USA: National Center for Biotechnology Information. 27 March 2005. Identification and Related Records. Retrieved 3 March 2012.
  • ^ Merck Index of Chemicals and Drugs, 9th ed., monograph 5074
  • ^ Textbook of Practical Organic Chemistry, 5th Edition, Prentice Hall, 1989
  • t
  • e

  • Retrieved from "https://en.wikipedia.org/w/index.php?title=Isopropyl_iodide&oldid=1109418828"
     



    Last edited on 9 September 2022, at 18:20  





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    This page was last edited on 9 September 2022, at 18:20 (UTC).

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