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Rubidium nitrate





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Rubidium nitrate is an inorganic compound with the formula RbNO3. This alkali metal nitrate salt is white and highly soluble in water.

Rubidium nitrate
Unit cell

Unit cell of rubidium nitrate

Names
IUPAC name

Rubidium nitrate

Identifiers

CAS Number

3D model (JSmol)

ChemSpider
ECHA InfoCard 100.032.767 Edit this at Wikidata
EC Number
  • 236-060-1

PubChem CID

RTECS number
  • QV0900000

CompTox Dashboard (EPA)

  • InChI=1S/NO3.Rb/c2-1(3)4;/q-1;+1 checkY

    Key: RTHYXYOJKHGZJT-UHFFFAOYSA-N checkY

  • InChI=1S/NO3.Rb/c2-1(3)4;/q-1;+1

    Key: RTHYXYOJKHGZJT-UHFFFAOYAE

  • Key: RTHYXYOJKHGZJT-UHFFFAOYSA-N

  • [Rb+].[O-][N+]([O-])=O

Properties

Chemical formula

RbNO3
Molar mass 147.473 g/mol
Appearance White hygroscopic solid
Density 3.11 g/cm3
Melting point 310 °C (590 °F; 583 K) decomposes
Boiling point 578 °C (1,072 °F; 851 K)

Solubility in water

44.28 g/100 mL (16 °C)
65.0 g/100 mL (25 °C)[1]

Magnetic susceptibility (χ)

−41.0·10−6cm3/mol

Refractive index (nD)

1.524
Structure[2]

Crystal structure

trigonal

Space group

P31

Lattice constant

a = 10.474 Å, c = 7.443 Å

Lattice volume (V)

707.2 Å3
Hazards
Occupational safety and health (OHS/OSH):

Main hazards

Oxidant
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 1: Exposure would cause irritation but only minor residual injury. E.g. turpentineFlammability 0: Will not burn. E.g. waterInstability 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g. liquid nitrogenSpecial hazard OX: Oxidizer. E.g. potassium perchlorate
1
0
0
Flash point Non-flammable
Lethal dose or concentration (LD, LC):

LD50 (median dose)

4625 mg/kg (rat, oral)
Related compounds

Other anions

Rubidium sulfate
Rubidium chloride

Other cations

Lithium nitrate
Sodium nitrate
Potassium nitrate
Caesium nitrate

Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

checkY verify (what is checkY☒N ?)

Infobox references

Properties

edit
 
Solubility of rubidium nitrate in water

Rubidium nitrate is a white crystalline powder that is highly soluble in water and very slightly soluble in acetone. In a flame test, RbNO3 gives a mauve/light purple colour.

Uses

edit

Rubidium compounds have very few applications.[1] Like caesium nitrate, it is used in infrared radiation optics, in pyrotechnic compositions as a pyrotechnic colorant and as an oxidizer, e.g.indecoys and illumination flares although it is rarely used in fireworks to produce a red-violet colour. It is also used as a raw material for preparation of other rubidium compounds and rubidium metal, for manufacture of catalysts and in scintillation counters.

Production

edit

RbNO3 can be prepared either by dissolving rubidium metal, its hydroxide or carbonate in nitric acid.

RbOH + HNO3 → RbNO3 + H2O
Rb2CO3 + 2 HNO3 → 2 RbNO3 + CO2 + H2O
2 Rb + 2 HNO3 → 2 RbNO3 + H2

References

edit
  1. ^ a b W. Lenk, H. Prinz, A. Steinmetz,"Rubidium and Rubidium Compounds" in Ullmann's Encyclopedia of Industrial Chemistry, 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. doi:10.1002/14356007.a23_473.pub2
  • ^ Jutta Pohl, Dieter Pohl, Gunadi Adiwidjaja (1992). "Phase Transition in Rubidium Nitrate at 346 K and Structure at 296, 372, 413 and 437 K". Acta Crystallographica Section B. B48 (2): 160–166. doi:10.1107/S0108768191013459.{{cite journal}}: CS1 maint: multiple names: authors list (link)

  • Retrieved from "https://en.wikipedia.org/w/index.php?title=Rubidium_nitrate&oldid=1216862067"
     



    Last edited on 2 April 2024, at 12:21  





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    This page was last edited on 2 April 2024, at 12:21 (UTC).

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