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S-Adenosylmethioninamine





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S-Adenosylmethioninamine is a substrate that is required for the biosynthesis of polyamines including spermidine, spermine, and thermospermine.[1] It is produced by decarboxylationofS-adenosyl methionine.

S-Adenosylmethioninamine
Names
IUPAC name

S-(3-Aminopropyl)-S-methyl-5′-thioadenosin-5′-ium

Systematic IUPAC name

(3-Aminopropyl){[(2S,3S,4R,5R)-5-(6-amino-9H-purin-9-yl)-3,4-dihydroxyoxolan-2-yl]methyl}methylsulfanium

Other names

S-Adenosyl-(5′)-3-methylthiopropylamine
decarboxylated S-adenosyl methionine
decarboxy-S-adenosyl methionine
(5-Deoxy-5-adenosyl)(3-aminopropyl)methylsulfonium cation

Identifiers

CAS Number

3D model (JSmol)

Abbreviations dAdoMet, dc-SAM
ChEBI
ChemSpider
KEGG

PubChem CID

UNII

CompTox Dashboard (EPA)

  • InChI=1S/C14H23N6O3S/c1-24(4-2-3-15)5-8-10(21)11(22)14(23-8)20-7-19-9-12(16)17-6-18-13(9)20/h6-8,10-11,14,21-22H,2-5,15H2,1H3,(H2,16,17,18)/q+1/t8-,10-,11-,14-,24?/m1/s1 ☒N

    Key: ZUNBITIXDCPNSD-LSRJEVITSA-N ☒N

  • InChI=1/C14H23N6O3S/c1-24(4-2-3-15)5-8-10(21)11(22)14(23-8)20-7-19-9-12(16)17-6-18-13(9)20/h6-8,10-11,14,21-22H,2-5,15H2,1H3,(H2,16,17,18)/q+1/t8-,10-,11-,14-,24?/m1/s1

    Key: ZUNBITIXDCPNSD-LSRJEVITBK

  • C[S+](CCCN)C[C@@H]1[C@H]([C@H]([C@@H](O1)n2cnc3c2ncnc3N)O)O

Properties

Chemical formula

C14H23N6O3S+
Molar mass 355.43582 g/mol

Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

☒N verify (what is checkY☒N ?)

Infobox references

See also

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References

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  1. ^ Takahashi, Taku; Kakehi, Jun-Ichi (2009-10-13). "Polyamines: Ubiquitous polycations with unique roles in growth and stress responses". Annals of Botany. 105 (1): 1–6. doi:10.1093/aob/mcp259. PMC 2794062. PMID 19828463.


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    Last edited on 17 October 2023, at 03:21  





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    This page was last edited on 17 October 2023, at 03:21 (UTC).

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