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Does anyone know easier steps to get the synthesis of Thionyl chloride??
we are getting the coloured(reddish/marun colour)impurities during manufacturing of thionyl chloride. what is the reason for this? if any one can find then send me at following email address : alpesh20002001@yahoo.co.in
thanks
Does anyone know why thionyl bromide is listed as an anion under related compounds?Haligonian1 14:14, 14 June 2007 (UTC)Reply
I think the new grahics have phosgene instead of thionyl chloride as a reagent, maybe this could be changed. I'm with gerrit (talk) 21:34, 21 January 2008 (UTC)Reply
Not sure if this is where I post this but the mechanism posted for acetyl chloride synthesis is incorrect, someone fix it I don't have time.
The structure that is shown is incorrect. In particular, the S-Cl are way too short. I have performed a variety of quantum mechanical calculations of this molecule and in all cases the S-Cl bond is around 200 pm. That is quite comparable to the sum of the covalent radii of the two atoms. I have built a Jmol page showing the structure and the bond lengths and angles from a DFT/B3LYP calculation using the 6311_G(d) basis set. It is at [1]. Wfcoleman (talk) 18:33, 18 February 2009 (UTC)Reply
Here we go: J. Mol. Struct. (1983) 101 233-238. MW data: (S=O) = (1.4278±0.0005) Å, d(S-Cl) = (2.0744±0.0003) Å, ∠Cl-S-Cl = (96.9547±0.0013)°, ∠O=S-Cl (107.958±0.022)°.
New image on the way.
Ben (talk) 19:23, 18 February 2009 (UTC)Reply
The comment(s) below were originally left at Talk:Thionyl chloride/Comments, and are posted here for posterity. Following several discussions in past years, these subpages are now deprecated. The comments may be irrelevant or outdated; if so, please feel free to remove this section.
The structure shown for thionyl chloride is incorrect. In particular the S-Cl bonds are much shorter than they should be. My calculations at the DFT/B3LYP level using the 6311-G(d) basis set show the bond lengths to be about 200 pm. The bond length is similar in a variety of Hartree-Fock and DFT methods, and is consistent with the sum of the covalent radii of the two atoms. The structure is shown at [2]. Wfcoleman (talk) 17:50, 18 February 2009 (UTC)Reply |
Last edited at 17:50, 18 February 2009 (UTC). Substituted at 08:34, 30 April 2016 (UTC)
I check pages listed in Category:Pages with incorrect ref formatting to try to fix reference errors. One of the things I do is look for content for orphaned references in wikilinked articles. I have found content for some of Thionyl chloride's orphans, the problem is that I found more than one version. I can't determine which (if any) is correct for this article, so I am asking for a sentient editor to look it over and copy the correct ref content into this article.
Reference named "clayden":
I apologize if any of the above are effectively identical; I am just a simple computer program, so I can't determine whether minor differences are significant or not. AnomieBOT⚡ 18:25, 7 August 2020 (UTC)Reply
It plays a role in the movie Ruby Cairo. Is this at all worth mentioning in the article? Kdammers (talk) 19:10, 11 June 2023 (UTC)Reply