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Triphenyltin hydroxide





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Triphenyltin hydroxide is an organotin compound with formula Sn(C6H5)3OH. Triphenyltin hydroxide is used as a fungicide for potatoes, sugar beets, and pecans. It was first registered for use as a pesticide in the United States in 1971.[1]

Triphenyltin hydroxide
Skeletal formula of triphenyltin hydroxide
Space-filling model of the triphenyltin hydroxide molecule
Names
Preferred IUPAC name

Triphenylstannanol

Identifiers

CAS Number

3D model (JSmol)

Beilstein Reference

4139186
ChEBI
ChEMBL
ChemSpider
ECHA InfoCard 100.000.901 Edit this at Wikidata
EC Number
  • 200-990-6

Gmelin Reference

7194
KEGG

PubChem CID

RTECS number
  • WH8575000
UNII
UN number 2786 2588

CompTox Dashboard (EPA)

  • InChI=1S/3C6H5.H2O.Sn/c3*1-2-4-6-5-3-1;;/h3*1-5H;1H2;/q;;;;+1/p-1 checkY

    Key: BFWMWWXRWVJXSE-UHFFFAOYSA-M checkY

  • InChI=1/3C6H5.H2O.Sn/c3*1-2-4-6-5-3-1;;/h3*1-5H;1H2;/q;;;;+1/p-1/rC18H16OSn/c19-20(16-10-4-1-5-11-16,17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15,19H

    Key: BFWMWWXRWVJXSE-OLMCWIPIAE

  • O[Sn](c1ccccc1)(c2ccccc2)c3ccccc3

Properties

Chemical formula

C18H16OSn
Molar mass 367.035 g·mol−1
Hazards
GHS labelling:

Pictograms

GHS05: CorrosiveGHS06: ToxicGHS07: Exclamation markGHS08: Health hazardGHS09: Environmental hazard

Signal word

Danger

Hazard statements

H301, H311, H315, H318, H330, H335, H351, H361, H372, H410

Precautionary statements

P201, P202, P260, P261, P264, P270, P271, P273, P280, P281, P284, P301+P310, P302+P352, P304+P340, P305+P351+P338, P308+P313, P310, P312, P314, P320, P321, P322, P330, P332+P313, P361, P362, P363, P391, P403+P233, P405, P501

Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

☒N verify (what is checkY☒N ?)

Infobox references

Structure

edit
 
Structure of solid triphenyltin hydroxide.

While triphenyltin hydroxide is often depicted as a monomer, it crystallizes as a polymer with a bridging hydroxide groups.[2] The Sn-O distances are 2.18 and 2.250 Å. Many organotin compounds engage in similar aggregation equilibria.

References

edit
  1. ^ "R.E.D. Facts: Triphenyltin Hydroxide" (PDF). U.S. EPA.
  • ^ Christopher Glidewell; John N. Low; João A. S. Bomfim; Carlos A. L. Filgueiras; James L. Wardell (2002). "catena-Poly[[triphenyltin(IV)]-μ-hydroxo-κ2O:O] at 120 K". Acta Crystallographica Section C: Crystal Structure Communications. 58 (Pt 4): M199-201. doi:10.1107/S0108270102001798. PMID 11932514.

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  • Retrieved from "https://en.wikipedia.org/w/index.php?title=Triphenyltin_hydroxide&oldid=1177944795"
     



    Last edited on 30 September 2023, at 16:53  





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    This page was last edited on 30 September 2023, at 16:53 (UTC).

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