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Cyclo(18)carbon






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This is an old revision of this page, as edited by ZxxZxxZ (talk | contribs)at14:55, 16 August 2019 (content partially copied from the article cyclocarbon). The present address (URL) is a permanent link to this revision, which may differ significantly from the current revision.
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Cyclo(18)carbon
Properties

Chemical formula

C18
Molar mass 216.198 g·mol−1

Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Infobox references

Cyclooctadeca-1,3,5,7,9,11,13,15,17-hexayneorcyclo[18]carbon is a chemical compound, an allotropeofcarbon with molecular formulaC18. The molecule is a ring of eightteen carbon atoms, connected by alternating triple and single bonds; thus, it is a cyclocarbon.

Cyclo[18]carbon is the smallest cyclo[n]carbon predicted to be thermodynamically stable, with a computed strain energy of 72 kilocalories per mole.[1][2]

An IBM/Oxford team claimed to synthesize it in solid state in 2019:[3]

Synthesis of cyclocarbon
Synthesis of cyclocarbon

The reaction was performed using electric currents.[4]

According to these IBM researchers, the synthesized cyclocarbon has alternating triple and single bonds, rather than being made of entirely of double bonds. This supposedly makes this molecule a semiconductor.[4]

References

  1. ^ George A. Adamson; Charles W. Rees (1996). "Towards the total synthesis of cyclo[n]carbons and the generation of cyclo[6]carbon". J. Chem. Soc., Perkin Trans. 1 (13): 1535–1543. doi:10.1039/P19960001535.
  • ^ Cite error: The named reference diederich89 was invoked but never defined (see the help page).
  • ^ Kaiser, Katharina (15 Aug 2019). "An sp-hybridized molecular carbon allotrope, cyclo[18]carbon". Science. doi:10.1126/science.aay1914.
  • ^ a b Castelvecchi, Davide (15 August 2019). "Chemists make first-ever ring of pure carbon". Nature. doi:10.1038/d41586-019-02473-z. Retrieved 16 August 2019.

  • Retrieved from "https://en.wikipedia.org/w/index.php?title=Cyclo(18)carbon&oldid=911105015"

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    This page was last edited on 16 August 2019, at 14:55 (UTC).

    This version of the page has been revised. Besides normal editing, the reason for revision may have been that this version contains factual inaccuracies, vandalism, or material not compatible with the Creative Commons Attribution-ShareAlike License.



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