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1 References  














Alaninol






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From Wikipedia, the free encyclopedia
 


Alaninol
Names
Preferred IUPAC name

2-Aminopropan-1-ol

Identifiers

CAS Number

  • (S): 2749-11-3 checkY
  • (R): 35320-23-1 checkY
  • 3D model (JSmol)

    ChEBI
    ChEMBL
    ChemSpider
    ECHA InfoCard 100.025.644 Edit this at Wikidata
    EC Number
    • (S): 220-388-7

    PubChem CID

    UNII
  • (S): V403GH89L1 checkY
  • (R): 770ZI70L3Q checkY
  • CompTox Dashboard (EPA)

    • (S): InChI=1S/C3H9NO/c1-3(4)2-5/h3,5H,2,4H2,1H3/t3-/m0/s1

      Key: BKMMTJMQCTUHRP-VKHMYHEASA-N

    • (S): CC(CO)N

    Properties

    Chemical formula

    C3H9NO
    Molar mass 75.111 g·mol−1
    Appearance colorless solid
    Melting point 96 °C racemate
    72-72 °C for R or S
    Boiling point 174.5 °C (346.1 °F; 447.6 K)
    Hazards
    GHS labelling:

    Pictograms

    GHS05: Corrosive

    Signal word

    Danger

    Hazard statements

    H314

    Precautionary statements

    P260, P264, P280, P301+P330+P331, P303+P361+P353, P304+P340, P305+P351+P338, P310, P321, P363, P405, P501

    Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

    Infobox references

    Alaninol is the organic compound with the formula CH3CH(NH2)CH2OH. A colorless solid, the compound is classified as an amino alcohol. It can be generated by converting the carboxylic group of alanine to an alcohol with a strong reducing agent such as lithium aluminium hydride.[1] The compound is chiral, and as is normal for chiral compounds, the physical properties of the racemate differ somewhat from those of the enantiomers. It is a precursor to numerous chiral ligands used in asymmetric catalysis.[2] The compound is an example of a 1,2-ethanolamine.[3]

    References[edit]

    1. ^ Dickman, D.A.; Meyers, A.I.; Smith, G.A.; Gawley, R.E. (1990). "Reduction of α-Amino Acids". Organic Syntheses. 7: 530. doi:10.15227/orgsyn.063.0136. Retrieved 21 December 2022.
  • ^ Dawson, Graham J.; Frost, Christopher G.; Williams, Jonathan M.J.; Coote, Steven J. (1993). "Asymmetric palladium catalysed allylic substitution using phosphorus containing oxazoline ligands". Tetrahedron Letters. 34 (19): 3149–3150. doi:10.1016/S0040-4039(00)93403-8.
  • ^ Martin Ernst; Johann-Peter Melder; Franz Ingo Berger; Christian Koch (2022). "Ethanolamines and Propanolamines". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi:10.1002/14356007.a10_001.pub2. ISBN 978-3527306732.

  • Retrieved from "https://en.wikipedia.org/w/index.php?title=Alaninol&oldid=1197721770"

    Category: 
    Amino alcohols
    Hidden categories: 
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