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Contents

   



(Top)
 


1 Synthesis  





2 Structure  





3 References  














Arsenic tetroxide






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From Wikipedia, the free encyclopedia
 


Arsenic tetroxide
Names
IUPAC name

Arsenic(III,V) dioxide

Identifiers

CAS Number

3D model (JSmol)

ChemSpider

PubChem CID

CompTox Dashboard (EPA)

  • InChI=1S/2As.4O/q+3;+5;;;;

    Key: RAKBAHUVRSFKQD-UHFFFAOYSA-N

  • [O]=[As][O][As](=O)=O

Properties

Chemical formula

As2O4
Molar mass 213.839 g·mol−1
Hazards
NIOSH (US health exposure limits):

PEL (Permissible)

[1910.1018] TWA 0.010 mg/m3[1]

REL (Recommended)

Ca C 0.002 mg/m3 [15-minute][1]

IDLH (Immediate danger)

Ca [5 mg/m3 (as As)][1]

Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Infobox references

Arsenic tetroxide is an inorganic compound with the chemical formulaAs2O4, containing As(III) and As(V), AsIIIAsVO4.[2]

Synthesis[edit]

It can be synthesized in an autoclave via the following reaction:

2As
2
O
3
+ O
2
→ 2 As
2
O
4

Structure[edit]

It adopts a layer structure, and the coordination geometry of As(III) is triangular pyramid while As(V) is tetrahedral.[2]

References[edit]

  1. ^ a b c NIOSH Pocket Guide to Chemical Hazards. "#0038". National Institute for Occupational Safety and Health (NIOSH).
  • ^ a b Jones, P. G.; Beesk, W.; Sheldrick, G. M.; Sharman, E. (14 February 1980). "Arsenic dioxide". Acta Crystallographica Section B. 36 (2): 439–440. doi:10.1107/S0567740880003433.
  • t
  • e

  • Retrieved from "https://en.wikipedia.org/w/index.php?title=Arsenic_tetroxide&oldid=1224114893"

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    Mixed valence compounds
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    This page was last edited on 16 May 2024, at 10:14 (UTC).

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