Atomic coherence is the induced coherence between levels of a multi-level atomic system.
The internal state of an atom is characterized by a superposition of excited states and their associated energy levels. In the presence of external electromagnetic fields, the atom's energy levels acquire perturbations to the excited states that describe the atom's internal state. When the acquired phase is the same over the range of internal states, the atom is coherent. Atomic coherence is characterized by the length of time over which the internal state of the atom can be reliably manipulated.[1]
If an electron in a two level atomic system is excited by narrow line width coherent electro-magnetic radiation, like a laser, that is on resonance with the two level transition, the electron will Rabi flop. During Rabi flopping the electron oscillates between the ground and excited states and can be described by a continuous rotation around the Bloch sphere.
For a perfectly isolated system the Rabi oscillation will continue indefinitely and will undergo no phase change, making it a "coherent state".[5] In physical systems interactions between the system and the environment introduce an unknown phase in the Rabi oscillation between the two levels with respect to the Rabi oscillation in the perfectly isolated system causing "decoherence".
Rabi flopping between the S1/2 and D5/2 energy states in 88Sr+. This example shows high fidelity Rabi flopping on the clock transition with little decoherence.
If instead of a single two-level system an ensemble of identical two level systems (such as a chain of identical atoms in an ion trap) is prepared and continuously addressed with a laser, all the atoms may begin to simultaneously Rabi flop.[citation needed] At the beginning all two level systems will have a defined relative phase relation (they will all be in phase) and the system will be coherent.
As atoms begin to undergo random spontaneous emission their Rabi oscillations will accumulate a random relative phase with respect to each other and become decoherent. In actual experiments ambient magnetic field noise and thermal heating from collisions between atoms cause decoherence faster than random spontaneous emission and are the dominant uncertainties when running atomic clocksortrapped ion quantum computers.[6] Atomic coherence can also apply to multi-level systems which require more than a single laser.
^Wineland, D.J.; Monroe, C.; Itano, W.M.; Leibfried, D.; King, B.E.; Meekhof, D.M. (May 1998). "Experimental issues in coherent quantum-state manipulation of trapped atomic ions". Journal of Research of the National Institute of Standards and Technology. 103 (3): 259. doi:10.6028/jres.103.019.
