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1 References  














Chlorophyll d






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Chlorophyll d
Identifiers

CAS Number

3D model (JSmol)

ChEBI
ChemSpider

PubChem CID

  • 16070025
  • UNII

    CompTox Dashboard (EPA)

    • InChI=1S/C54H71N4O6.Mg/c1-12-38-34(7)42-27-46-40(29-59)36(9)41(56-46)26-43-35(8)39(51(57-43)49-50(54(62)63-11)53(61)48-37(10)44(58-52(48)49)28-45(38)55-42)22-23-47(60)64-25-24-33(6)21-15-20-32(5)19-14-18-31(4)17-13-16-30(2)3;/h24,26-32,35,39,50H,12-23,25H2,1-11H3,(H-,55,56,57,58,59,61);/q-1;+2/p-1/b33-24+;/t31-,32-,35+,39+,50-;/m1./s1 checkY

      Key: QXWRYZIMSXOOPY-SKHCYZARSA-M checkY

    • InChI=1S/C54H71N4O6.Mg/c1-12-38-34(7)42-27-46-40(29-59)36(9)41(56-46)26-43-35(8)39(51(57-43)49-50(54(62)63-11)53(61)48-37(10)44(58-52(48)49)28-45(38)55-42)22-23-47(60)64-25-24-33(6)21-15-20-32(5)19-14-18-31(4)17-13-16-30(2)3;/h24,26-32,35,39,50H,12-23,25H2,1-11H3,(H-,55,56,57,58,59,61);/q-1;+2/p-1/b33-24+;/t31-,32-,35+,39+,50-;/m1./s1

    • CC(C)CCC[C@@H](C)CCC[C@@H](C)CCCC(\C)=C\COC(=O)CC[C@H]6[C@H](C)C=5/C=C/2\N\1[Mg]n4c(\C=C\3/N=C(/C=C/1C(\C=O)=C\2\C)C(/C)=C/3/CC)c(C)c7c4\C(=C6/N=5)[C@@H](C(=O)OC)C7=O

    Properties

    Chemical formula

    C54H70MgO6N4

    Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

    ☒N verify (what is checkY☒N ?)

    Infobox references

    Chlorophyll d (Chl d) is a form of chlorophyll, identified by Harold Strain and Winston Manning in 1943.[1] It was unambiguously identified in Acaryochloris marina in the 1990s.[2] It is present in cyanobacteria which use energy captured from sunlight for photosynthesis.[3] Chl d absorbs far-red light, at 710 nm wavelength, just outside the optical range.[4] An organism that contains Chl d is adapted to an environment such as moderately deep water, where it can use far red light for photosynthesis,[5] although there is not a lot of visible light.[6]

    Chl d is produced from chlorophyllide dbychlorophyll synthase. Chlorophyllide d is made from chlorophyllide a, but the oxygen-using enzyme that performs this conversion remains unknown as of 2022.[7]

    Ball-and-stick model Space-filling model

    References

    [edit]
    1. ^ Manning WM, Strain HH (November 1943). "Chlorophyll d, a green pigment of red algae" (PDF). Journal of Biological Chemistry. 151 (1): 1–9. doi:10.1016/S0021-9258(18)72109-1.
  • ^ Larkum AW, Kühl M (August 2005). "Chlorophyll d: the puzzle resolved" (PDF). Trends in Plant Science. 10 (8): 355–7. doi:10.1016/j.tplants.2005.06.005. PMID 16019251. Archived from the original (PDF) on 2012-03-13. Retrieved 2014-11-17.
  • ^ "Photosynthetic Pigments". University of California Museum of Paleontology.
  • ^ "Scientists discover first new chlorophyll in 60 years". PHYS ORG. August 20, 2010.
  • ^ "Researchers decode genetics of chlorophyll d". News Medical Life Sciences. AZO Network.
  • ^ "Chlorophyll d". Biology Online. 7 October 2019.
  • ^ Tsuzuki, Yuki; Tsukatani, Yusuke; Yamakawa, Hisanori; Itoh, Shigeru; Fujita, Yuichi; Yamamoto, Haruki (29 March 2022). "Effects of Light and Oxygen on Chlorophyll d Biosynthesis in a Marine Cyanobacterium Acaryochloris marina". Plants. 11 (7): 915. doi:10.3390/plants11070915. PMC 9003380. PMID 35406896.

  • Retrieved from "https://en.wikipedia.org/w/index.php?title=Chlorophyll_d&oldid=1188023500"

    Categories: 
    Tetrapyrroles
    Photosynthetic pigments
    Hidden categories: 
    Chemical articles with multiple compound IDs
    Multiple chemicals in an infobox that need indexing
    Chemical articles with multiple PubChem CIDs
    Articles without KEGG source
    Articles with changed ChemSpider identifier
    Articles containing unverified chemical infoboxes
    Chembox image size set
    Articles with short description
    Short description matches Wikidata
     



    This page was last edited on 2 December 2023, at 22:27 (UTC).

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