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One of the most studied atomic ordering is CuPt type ordering in III-V semiconductor alloyinchemistry and physics. It occurs in III-V alloy when the cation planes take an alternate sequence of A-rich and B-rich plane following AxB1−xC. The resulting structure is usually called as superlattice-like structure along [1-11] or [-111] – called (111) B plane, or along [-1-1-1] or [11-1] – called (111) A plane. The two ordering direction is thus called CuPt type A and B ordering.[citation needed]
The same type ordering is also observed in II-VI alloy such as CdZnTe alloy. The ordering sequence viewed on atomic planes along [-111] and [1-11] reveals Cd and Zn alternating planes.[citation needed]
This ordering reduces the lattice symmetry ordering to L11 and leads to change of its optical and electrical properties. The apparent effects are: band gap reduction, valence band splitting, and optical anisotropy. For instance, in CuPt type B ordering, the L point of the Brillouin zone fold back to the Γ-point, and the folded band “repels” the original conduction band minimum and bring down the bottom of conduction band.[citation needed]
AlInP epilayers grown by metal-organic vapour-phase epitaxy on GaAs substrates exhibit CuPt-B-type spontaneous atomic ordering.[2] Additionally, CuPt-type structures were observed in CdZnTe during metal-organic vapor phase epitaxy.[3]
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