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F r o m W i k i p e d i a , t h e f r e e e n c y c l o p e d i a
Europium(III) chromate is a chemical compound composed of europium , chromium and oxygen with europium in the +3 oxidation state , chromium in the +5 oxidation state and oxygen in the −2 oxidation state.[4] [3] It has the chemical formula of Eu Cr O 4 .
Preparation [ edit ]
To obtain europium(III) chromate, an equimolar solution of europium(III) acetate and chromium(IV ) oxide is dried in a vacuum at 70 °C and then heated to 400 °C in air.[2] [5] Another way to obtain europium(III) chromate is by reacting stoichiometric amounts of europium(III) nitrate hexahydrate and chromium(III) nitrate nonahydrate for 30 minutes at 433 K (160 °C; 320 °F), 30 minutes at 473 K (200 °C; 392 °F) and then 1 hour at 853 K (580 °C; 1,076 °F). A constant stream of oxygen is passed over the reaction mixture. An oxygen flow is used to stabilise the +5 oxidation state of chromium.[4]
Eu(NO 3 )3 ·6H2 O + Cr(NO 3 )3 ·9H2 O → EuCrO4 + 6 NO2 + 15 H2 O + O2
Properties [ edit ]
Europium(III) chromate crystallizes tetragonally with space group I 4 1 /amd (No. 141) with lattice parameters a = 722.134(1 ) and c = 632.896(1 ) pm with four formula units per unit cell .[2]
The Néel temperature of europium(III) chromate is 15.9 K (−257.2 °C; −431.0 °F).[4] Above 700 °C, europium(III) chromate begins to decompose into europium chromite (EuCrO3 ).[3]
2 EuCrO4 → 2 EuCrO3 + O2
References [ edit ]
^ G. Buisson, E. F. Bertaut, J. Mareschal (1964), "Etude cristallographique des composes TCrO4 (T = terre rare ou Y)", Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences (in German), vol. 259, pp. 411–413 {{citation }}
: CS1 maint: multiple names: authors list (link )
^ a b c Hidetaka Konno, Yoshitaka Aoki, Zoltán Klencsár, Attila Vértes, Makoto Wakeshima (2001-12-01). "Structure of EuCrO4 and Its Electronic and Magnetic Properties" . Bulletin of the Chemical Society of Japan . 74 (12 ): 2335–2341. doi :10.1246/bcsj.74.2335 . ISSN 0009-2673 . {{cite journal }}
: CS1 maint: multiple names: authors list (link )
^ a b c J. Thakur, R. Shukla, N. Raje, D. Ghonge, H. Bagla (2011-10-01). "Synthesis, Structural Characterization and Thermal Stability of Nanocrystalline Rare-Earth Chromates (RECrO4 ) and Rare-Earth Chromites (RECrO3 )" . Nanoscience and Nanotechnology Letters . 3 (5 ): 648–654. doi :10.1166/nnl.2011.1233 . {{cite journal }}
: CS1 maint: multiple names: authors list (link )
^ a b c E Jiménez, J Isasi, R Sáez-Puche (2000-11-01). "Synthesis, structural characterization and magnetic properties of RCrO4 oxides, R=Nd, Sm, Eu and Lu" . Journal of Alloys and Compounds . 312 (1–2): 53–59. doi :10.1016/S0925-8388(00 )01079-3 . {{cite journal }}
: CS1 maint: multiple names: authors list (link )
^ Yoshitaka Aoki, Hidetaka Konno, Hiroto Tachikawa, Michio Inagaki (2000-05-01). "Characterization of LaCrO4 and NdCrO4 by XRD, Raman Spectroscopy, and ab Initio Molecular Orbital Calculations" . Bulletin of the Chemical Society of Japan . 73 (5 ): 1197–1203. doi :10.1246/bcsj.73.1197 . ISSN 0009-2673 . {{cite journal }}
: CS1 maint: multiple names: authors list (link )
t
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Europium(II )
Europium(III)
t
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Chromium(0)
Chromium(I )
Organochromium(I ) compounds
Chromium(II )
Organochromium(II ) compounds
Chromium(II, III)
Chromium(III)
Chromium(IV )
Chromium(V )
Chromium(VI )
Polyatomic ion
R e t r i e v e d f r o m " https://en.wikipedia.org/w/index.php?title=Europium(III)_chromate&oldid=1201970099 "
C a t e g o r i e s :
● E u r o p i u m ( I I I ) c o m p o u n d s
● C h r o m a t e s
H i d d e n c a t e g o r i e s :
● C S 1 m a i n t : m u l t i p l e n a m e s : a u t h o r s l i s t
● C S 1 G e r m a n - l a n g u a g e s o u r c e s ( de )
● C h e m i c a l s w i t h o u t a P u b C h e m C I D
● A r t i c l e s w i t h o u t I n C h I s o u r c e
● C h e m i c a l p a g e s w i t h o u t C h e m S p i d e r I D
● A r t i c l e s w i t h o u t E B I s o u r c e
● A r t i c l e s w i t h o u t K E G G s o u r c e
● A r t i c l e s w i t h o u t U N I I s o u r c e
● A r t i c l e s c o n t a i n i n g u n v e r i f i e d c h e m i c a l i n f o b o x e s
● C h e m b o x a r t i c l e s w i t h o u t i m a g e
● A r t i c l e s w i t h s h o r t d e s c r i p t i o n
● S h o r t d e s c r i p t i o n m a t c h e s W i k i d a t a
● T h i s p a g e w a s l a s t e d i t e d o n 1 F e b r u a r y 2 0 2 4 , a t 1 9 : 2 1 ( U T C ) .
● T e x t i s a v a i l a b l e u n d e r t h e C r e a t i v e C o m m o n s A t t r i b u t i o n - S h a r e A l i k e L i c e n s e 4 . 0 ;
a d d i t i o n a l t e r m s m a y a p p l y . B y u s i n g t h i s s i t e , y o u a g r e e t o t h e T e r m s o f U s e a n d P r i v a c y P o l i c y . W i k i p e d i a ® i s a r e g i s t e r e d t r a d e m a r k o f t h e W i k i m e d i a F o u n d a t i o n , I n c . , a n o n - p r o f i t o r g a n i z a t i o n .
● P r i v a c y p o l i c y
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