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Contents

   



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1 Preparation  





2 Physical properties  





3 Chemical properties  





4 Uses  





5 References  














Lanthanum nitride






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From Wikipedia, the free encyclopedia
 


Lanthanum nitride
Names
IUPAC name

Azanylidynelanthanum

Other names

Lanthanum mononitride, lanthanum(III) nitride

Identifiers

CAS Number

3D model (JSmol)

ChemSpider
ECHA InfoCard 100.042.936 Edit this at Wikidata
EC Number
  • 247-245-1

PubChem CID

CompTox Dashboard (EPA)

  • InChI=1S/La.N

    Key: QCLQZCOGUCNIOC-UHFFFAOYSA-N

  • [La+3].[N-3]

Properties

Chemical formula

LaN
Molar mass 152.912 g·mol−1
Appearance Black powder
Density 6.73 g/cm3
Melting point 2,450 °C (4,440 °F; 2,720 K)

Solubility in water

Insoluble
Hazards
GHS labelling:

Pictograms

GHS07: Exclamation mark

Signal word

Warning

Hazard statements

H315, H319, H335

Precautionary statements

P264, P271, P280, P302, P304, P305, P312, P313, P332, P338, P340, P351, P352, P362, P501

Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Infobox references

Lanthanum nitride is a binary inorganic compoundoflanthanum and nitride with the chemical formula LaN.[1][2]

Preparation[edit]

Lanthanum nitride can be prepared from the reaction of nitrogen and lanthanum trihydride:

2LaH3 + N2 → 2LaN + 3H2

It can also be prepared from the reaction of ammonia and lanthanum trihydride:[3]

LaH3 + NH3 → LaN + 3H2

The reaction of nitrogen and lanthanum amalgam can also work:[4]

2La + N2 → 2LaN

Physical properties[edit]

Lanthanum nitride forms black powder that is insoluble in water.[1] Their crystals are of the cubic system with the Fm3m space group.[5]

It is paramagnetic.

Chemical properties[edit]

Lanthanum nitride reacts with water and moisture from the air:[6]

LaN + 3H2O → La(OH)3 + NH3

It reacts with acids:

LaN + 4HCl → LaCl3 + NH4Cl

Uses[edit]

Gerbicidum. LaN is used as a LED material, magnetic material, semiconductor, refractory material, dyes, catalyst.[7][8]

References[edit]

  1. ^ a b "Lanthanum Nitride". American Elements. Retrieved 8 February 2024.
  • ^ Derz, Friedrich W. (18 May 2020). H-Z. Walter de Gruyter GmbH & Co KG. p. 1179. ISBN 978-3-11-232209-3. Retrieved 8 February 2024.
  • ^ Foster, L. S. (1945). The Preparation of Crucibles from Nitrides. U.S. Atomic Energy Commission. Technical Information Service. p. 8. Retrieved 8 February 2024.
  • ^ Young, R. A.; Ziegler, W. T. (November 1952). "Crystal Structure of Lanthanum Nitride 1,2". Journal of the American Chemical Society. 74 (21): 5251–5253. doi:10.1021/ja01141a004. ISSN 0002-7863. Retrieved 8 February 2024.
  • ^ Young, R. A.; Ziegler, W. T. (November 1952). "Crystal Structure of Lanthanum Nitride 1,2". Journal of the American Chemical Society. 74 (21): 5251–5253. doi:10.1021/ja01141a004. ISSN 0002-7863. Retrieved 8 February 2024.
  • ^ "Lanthanum Nitride Powder, LaN, CAS 25764-10-7 - Heeger Materials". Heeger Materials Inc. Retrieved 8 February 2024.
  • ^ "Lanthanum Nitride (LaN) Powder (CAS No. 25764-10-7)". samaterials.com. Retrieved 8 February 2024.
  • ^ Deng, Zihao; Kioupakis, Emmanouil (1 June 2021). "Semiconducting character of LaN: Magnitude of the bandgap and origin of the electrical conductivity". AIP Advances. 11 (6). arXiv:2106.04646. Bibcode:2021AIPA...11f5312D. doi:10.1063/5.0055515. S2CID 235376911. Retrieved 8 February 2024.

  • Retrieved from "https://en.wikipedia.org/w/index.php?title=Lanthanum_nitride&oldid=1230317528"

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    This page was last edited on 22 June 2024, at 01:13 (UTC).

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