Jump to content
 







Main menu
   


Navigation  



Main page
Contents
Current events
Random article
About Wikipedia
Contact us
Donate
 




Contribute  



Help
Learn to edit
Community portal
Recent changes
Upload file
 








Search  

































Create account

Log in
 









Create account
 Log in
 




Pages for logged out editors learn more  



Contributions
Talk
 



















Contents

   



(Top)
 


1 Physical properties  





2 Chemical properties  





3 References  














Osmium heptafluoride






Русский
ி
 

Edit links
 









Article
Talk
 

















Read
Edit
View history
 








Tools
   


Actions  



Read
Edit
View history
 




General  



What links here
Related changes
Upload file
Special pages
Permanent link
Page information
Cite this page
Get shortened URL
Download QR code
Wikidata item
 




Print/export  



Download as PDF
Printable version
 
















Appearance
   

 






From Wikipedia, the free encyclopedia
 


Osmium heptafluoride
Names
Other names

Osmium(VII) fluoride

Identifiers

CAS Number

3D model (JSmol)

  • InChI=1S/7FH.Os/h7*1H;/q;;;;;;;+7/p-7

    Key: PYLQBEQBIUJFFB-UHFFFAOYSA-G

  • F[Os](F)(F)(F)(F)(F)F

Properties

Chemical formula

F7Os
Molar mass 323.22 g·mol−1
Structure

Crystal structure

Pentagonal bipiramidal (calculated)[1]
Related compounds

Related compounds

Rhenium heptafluoride

Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Infobox references

Osmium heptafluoride is a possible inorganic chemical compound of osmium metal and fluorine with the chemical formula OsF
7
.[2][3] It was first reported in 1966 by the reaction of fluorine and osmium at 600 °C and 400 atm,[4] but no purported synthesis could be reproduced in 2006, giving only osmium hexafluoride instead.[5]

Physical properties[edit]

If it exists, osmium(VII) fluoride is supposedly a bluish-yellow hygroscopic substance, extremely unstable.[6] The compound starts decomposing at –100 °C. It should be stored in a nickel vessel at the temperature of liquid nitrogen.

Chemical properties[edit]

Osmium heptafluoride decomposes to osmium hexafluoride when slightly heated:

2OsF7  → 2OsF6 + F2

References[edit]

  1. ^ Bayerische Julius-Maximilians-Universität Würzburg (2006). The Highest Oxidation States of the 5d Transition Metals: a Quantum-Chemical Study (PDF) (Report). Chemical Society. Retrieved 2011-06-20.
  • ^ "Osmium heptafluoride". WebElements. Retrieved 19 April 2023.
  • ^ Hawkins, Donald T. (6 December 2012). Binary Fluorides: Free Molecular Structures and Force Fields A Bibliography (1957–1975). Springer Science & Business Media. p. 42. ISBN 978-1-4684-6147-3. Retrieved 19 April 2023.
  • ^ Glemser, Oskar; Roesky, Herbert W.; Hellberg, Karl-Heinz; Werther, Heinz-Ulrich (1966). "Darstellung und Eigenschaften von Osmiumheptafluorid". Chemische Berichte. 99 (8). Wiley: 2652–2662. doi:10.1002/cber.19660990834. ISSN 0009-2940.
  • ^ Shorafa, Hashem; Seppelt, Konrad (1 September 2006). "Osmium(VII) Fluorine Compounds". Inorganic Chemistry. 45 (19): 7929–7934. doi:10.1021/ic0608290. PMID 16961386.
  • ^ Edwards, A. J. (1 November 1983). "Structures of the binary fluorides". Advances in Inorganic Chemistry. 27. Academic Press: 108. ISBN 9780080578767. Retrieved 19 April 2023.
  • t
  • e

  • Retrieved from "https://en.wikipedia.org/w/index.php?title=Osmium_heptafluoride&oldid=1232226699"

    Categories: 
    Osmium compounds
    Fluorides
    Metal halides
    Hypothetical chemical compounds
    Inorganic compound stubs
    Hidden categories: 
    Chemicals without a PubChem CID
    Articles without InChI source
    Chemical pages without ChemSpiderID
    Articles without EBI source
    Articles without KEGG source
    Articles without UNII source
    Articles containing unverified chemical infoboxes
    Chembox articles without image
    Articles with short description
    Short description matches Wikidata
    All stub articles
     



    This page was last edited on 2 July 2024, at 16:48 (UTC).

    Text is available under the Creative Commons Attribution-ShareAlike License 4.0; additional terms may apply. By using this site, you agree to the Terms of Use and Privacy Policy. Wikipedia® is a registered trademark of the Wikimedia Foundation, Inc., a non-profit organization.



    Privacy policy

    About Wikipedia

    Disclaimers

    Contact Wikipedia

    Code of Conduct

    Developers

    Statistics

    Cookie statement

    Mobile view



    Wikimedia Foundation
    Powered by MediaWiki