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Contents

   



(Top)
 


1 Preparation  





2 References  














Phenidone






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From Wikipedia, the free encyclopedia
 


Phenidone
Names
Preferred IUPAC name

1-Phenylpyrazolidin-3-one

Identifiers

CAS Number

3D model (JSmol)

ChEMBL
ChemSpider
ECHA InfoCard 100.001.960 Edit this at Wikidata
EC Number
  • 202-155-1

PubChem CID

UNII

CompTox Dashboard (EPA)

  • InChI=1S/C9H10N2O/c12-9-6-7-11(10-9)8-4-2-1-3-5-8/h1-5H,6-7H2,(H,10,12) checkY

    Key: CMCWWLVWPDLCRM-UHFFFAOYSA-N checkY

  • InChI=1/C9H10N2O/c12-9-6-7-11(10-9)8-4-2-1-3-5-8/h1-5H,6-7H2,(H,10,12)

    Key: CMCWWLVWPDLCRM-UHFFFAOYAF

  • O=C2NN(c1ccccc1)CC2

Properties

Chemical formula

C9H10N2O
Molar mass 162.192 g·mol−1
Appearance Crystal leaflets or needles
Melting point 121 °C (250 °F; 394 K)

Solubility in water

10 g/100 ml at 100 °C
Solubilityinethanol 10 g/100 ml (hot)
Solubilityindiethyl ether practically insoluble
Hazards
Occupational safety and health (OHS/OSH):

Main hazards

Harmful if swallowed
GHS labelling:

Pictograms

GHS07: Exclamation markGHS09: Environmental hazard

Signal word

Warning

Hazard statements

H302, H411

Precautionary statements

P264, P270, P273, P301+P312, P330, P391, P501
Safety data sheet (SDS) External MSDS

Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

checkY verify (what is checkY☒N ?)

Infobox references

Phenidone (1-phenyl-3-pyrazolidinone) is an organic compound that is primarily used as a photographic developer. It has five to ten times the developing power as Metol. It also has low toxicity and unlike some other developers, does not cause dermatitis upon skin contact.[1]

Phenidone is Ilford's trademark for this material, which was first prepared in 1890. It was not until 1940 that J. D. Kendall, in the laboratories of Ilford Limited, discovered the reducing properties of this compound. Large scale production did not become feasible until 1951.[2]

Phenidone functions as a reducing agent. It converts to the N-phenyl-hydroxypyrazole:

Reaction of phenidone with silver bromide, as occurs in photographic development

Preparation

[edit]

Phenidone can be prepared by heating phenyl hydrazine with 3-chloropropanoic acid.[1]

References

[edit]
  1. ^ a b Merck Index of Chemicals and Drugs, 9th ed. monograph 7115
  • ^ Karlheinz Keller et al. "Photography" in Ullmann's Encyclopedia of Industrial Chemistry, 2005, Wiley-VCH, Weinheim. doi:10.1002/14356007.a20_001

  • Retrieved from "https://en.wikipedia.org/w/index.php?title=Phenidone&oldid=1191682676"

    Categories: 
    Photographic chemicals
    Pyrazolidines
    Lactams
    Phenyl compounds
    Substances discovered in the 19th century
    Hidden categories: 
    Articles without KEGG source
    ECHA InfoCard ID from Wikidata
    Chembox having GHS data
    Articles containing unverified chemical infoboxes
    Articles with short description
    Short description matches Wikidata
     



    This page was last edited on 25 December 2023, at 01:57 (UTC).

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