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Contents

   



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1 Synthesis  





2 Physical properties  





3 References  














Rhenium pentafluoride






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From Wikipedia, the free encyclopedia
 


Rhenium pentafluoride
Names
Other names

Rhenium(V) fluoride

Identifiers

CAS Number

3D model (JSmol)

PubChem CID

  • InChI=1S/5FH.Re/h5*1H;/q;;;;;+5/p-5

    Key: UKUWGTWCIFEMQK-UHFFFAOYSA-I

  • F[Re](F)(F)(F)F

Properties

Chemical formula

F5Re
Molar mass 281.199 g·mol−1
Appearance yellow-green crystals
Density g/cm3
Melting point 48 °C (118 °F; 321 K)
Boiling point 221.3 °C (430.3 °F; 494.4 K)

Solubility in water

reacts with water
Structure

Crystal structure

orthorhombic
Related compounds

Related compounds

Osmium pentafluoride

Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Infobox references

Rhenium pentafluoride is a binary inorganic compoundofrhenium and fluorine with the chemical formula ReF5.[1] This is a salt of rhenium and hydrofluoric acid.[2]

Synthesis[edit]

Rhenium pentafluoride can be synthesised by the reduction of rhenium hexafluoride with hydrogen, rhenium, or tungsten:

2ReF6 + H2 → 2ReF5 + 2HF
5ReF6 + Re → 6ReF5
6ReF6 + W → 6ReF5 + WF6

Physical properties[edit]

Rhenium pentafluoride forms yellow-green crystals[3]oforthorhombic crystal system, cell parameters a = 0.57 nm, b = 1.723 nm, c = 0.767 nm.

Rhenium pentafluoride reacts with water.

Rhenium pentafluoride is volatile. The compound consists of dimers of composition Re2F10.

References[edit]

  1. ^ Gutmann, Viktor (2 December 2012). Halogen Chemistry. Elsevier. p. 192. ISBN 978-0-323-14847-4. Retrieved 6 April 2023.
  • ^ Hawkins, Donald T. (6 December 2012). Binary Fluorides: Free Molecular Structures and Force Fields A Bibliography (1957–1975). Springer Science & Business Media. p. 50. ISBN 978-1-4684-6147-3. Retrieved 6 April 2023.
  • ^ Colton, Ray (1965). The Chemistry of Rhenium and Technetium. Interscience Publishers. p. 59. ISBN 978-0-470-16650-5. Retrieved 6 April 2023.

  • Retrieved from "https://en.wikipedia.org/w/index.php?title=Rhenium_pentafluoride&oldid=1192478295"

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    This page was last edited on 29 December 2023, at 16:10 (UTC).

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