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1 See also  





2 References  














Stannane






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Stannane
Structure and dimensions of the stannane molecule
Ball-and-stick model of the stannane molecule
Ball-and-stick model of the stannane molecule
Space-filling model of the stannane molecule
Space-filling model of the stannane molecule
  Tin, Sn
  Hydrogen, H
Names
IUPAC name

Stannane

Other names

tin tetrahydride
tin hydride

Identifiers

CAS Number

3D model (JSmol)

ChEBI
ChemSpider

PubChem CID

CompTox Dashboard (EPA)

  • InChI=1S/Sn.4H checkY

    Key: KXCAEQNNTZANTK-UHFFFAOYSA-N checkY

  • InChI=1/Sn.4H/rH4Sn/h1H4

    Key: KXCAEQNNTZANTK-GVMKXMNPAM

  • [Sn]

Properties

Chemical formula

SnH4
Molar mass 122.71 g/mol
Appearance colourless gas
Density 5.4 g/L, gas
Melting point −146 °C (−231 °F; 127 K)
Boiling point −52 °C (−62 °F; 221 K)
Structure

Molecular shape

Tetrahedral

Dipole moment

0 D
Thermochemistry

Heat capacity (C)

1.262 kJ/(kg·K)

Std enthalpy of
formation
fH298)

162.8 kJ/mol

Enthalpy of vaporization fHvap)

19.049 kJ/mol
Related compounds

Related organotins

tributylstannane (Bu3SnH)

Related compounds

Methane
Silane
Germane
Plumbane

Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

☒N verify (what is checkY☒N ?)

Infobox references

Stannane /ˈstænn/ortin hydride is an inorganic compound with the chemical formula SnH4. It is a colourless gas and the tin analogueofmethane. Stannane can be prepared by the reaction of SnCl4 and Li[AlH4].[1]

SnCl4 + Li[AlH4] → SnH4 + LiCl + AlCl3

Stannane decomposes slowly at room temperature to give metallic tin and hydrogen and ignites on contact with air.[1]

Variants of stannane can be found as a highly toxic, gaseous, inorganic metal hydrides and group 14 hydrides.

See also[edit]

References[edit]

  1. ^ a b Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. ISBN 978-0-08-037941-8.

Retrieved from "https://en.wikipedia.org/w/index.php?title=Stannane&oldid=1218538963"

Categories: 
Tin(IV) compounds
Metal hydrides
Reducing agents
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