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Vinylsilane refers to an organosilicon compound with chemical formula CH2 3 silane (SiH4 [1]
Substituted vinylsilanes [ edit ]
More commonly used than the parent vinylsilane are vinyl-substituted silanes with other substituents on silicon. In the area of organic synthesis , vinylsilanes are useful intermediates.[2]
Vinyltriethoxysilane is a common vinylsilane.
In the area of polymer chemistry and materials science , vinyltrimethoxysilane or vinyltriethoxysilane serve as monomers and coupling agents.
Preparation [ edit ]
Vinylsilanes are often prepared by hydrosilylation of alkynes . They can be made by the reaction of alkenyl lithium and Grignard reagents with chlorosilanes . In some cases dehydrogenative silylation is another method.[3]
References [ edit ]
^ Ring, M. A.; O'Neal, H. E.; Rickborn, S. F.; Sawrey, B. A. (1983). "Kinetics of the high-temperature thermal decomposition of silanes and alkylsilanes". Organometallics . 2 12 ): 1891–4. doi :10.1021/om50006a038 .
^ Fleming, Ian; Dunogues, Jacques; Smithers, Roger (1989). "The electrophilic substitution of allylsilanes and vinylsilanes". Organic Reactions . 37 doi :10.1002/0471264180.or037.02 . ISBN 0471264180
^ Lu, B.; Falck, J. R. (2010). "Iridium-Catalyzed (Z )-Trialkylsilylation of Terminal Olefins" . J. Org. Chem . 75 5 ): 1701–1705. doi :10.1021/jo902678p . PMC 2830331 PMID 20136153 .
R e t r i e v e d f r o m " https://en.wikipedia.org/w/index.php?title=Vinylsilane&oldid=1152492302 " C a t e g o r i e s : ● C a r b o s i l a n e s ● M o n o m e r s ● V i n y l c o m p o u n d s H i d d e n c a t e g o r i e s : ● A r t i c l e s w i t h o u t I n C h I s o u r c e ● C h e m i c a l p a g e s w i t h o u t C h e m S p i d e r I D ● A r t i c l e s w i t h o u t E B I s o u r c e ● A r t i c l e s w i t h o u t K E G G s o u r c e ● E C H A I n f o C a r d I D f r o m W i k i d a t a ● A r t i c l e s c o n t a i n i n g u n v e r i f i e d c h e m i c a l i n f o b o x e s ● A r t i c l e s w i t h s h o r t d e s c r i p t i o n ● S h o r t d e s c r i p t i o n m a t c h e s W i k i d a t a
● T h i s p a g e w a s l a s t e d i t e d o n 3 0 A p r i l 2 0 2 3 , a t 1 5 : 3 1 ( U T C ) . ● T e x t i s a v a i l a b l e u n d e r t h e C r e a t i v e C o m m o n s A t t r i b u t i o n - S h a r e A l i k e L i c e n s e 4 . 0 ;
a d d i t i o n a l t e r m s m a y a p p l y . B y u s i n g t h i s s i t e , y o u a g r e e t o t h e T e r m s o f U s e a n d P r i v a c y P o l i c y . W i k i p e d i a ® i s a r e g i s t e r e d t r a d e m a r k o f t h e W i k i m e d i a F o u n d a t i o n , I n c . , a n o n - p r o f i t o r g a n i z a t i o n . ● P r i v a c y p o l i c y ● A b o u t W i k i p e d i a ● D i s c l a i m e r s ● C o n t a c t W i k i p e d i a ● C o d e o f C o n d u c t ● D e v e l o p e r s ● S t a t i s t i c s ● C o o k i e s t a t e m e n t ● M o b i l e v i e w
