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1 Radiocarbon dating  














Wikipedia:Featured article candidates/Radiocarbon dating/archive1







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< Wikipedia:Featured article candidates

The article was promotedbyIan Rose via FACBot (talk) 05:42, 12 April 2015 (UTC) [1].[reply]


Radiocarbon dating[edit]

Nominator(s): Mike Christie (talk - contribs - library) 17:26, 6 March 2015 (UTC)[reply]

Radiocarbon dating has revolutionized archaeology, and the invention of the method earned Willard F. Libby a Nobel Prize. I've been working on the article for over a year, and I think it's now ready to be nominated here. It's benefitted from a peer review, where several editors helped improve the article; I would particularly like to thank Aa77zz and CorinneSD. Since then it's been copyedited by Eric Corbett. Three professional archaeologists have looked over the article, including one who specializes in the topic, and their comments have been addressed. The article is a departure from my previous nominations, which have all been in the humanities; I would like to make it clear that I have no special expertise in this area and wrote it as a layman. I hope you find the topic as interesting as I do. Mike Christie (talk - contribs - library) 17:26, 6 March 2015 (UTC)[reply]

Support As Mike mentions above, I took part in the peer review. This is an important article and Mike has done a fine job in bringing it up to the FA standard. Aa77zz (talk) 20:36, 6 March 2015 (UTC)[reply]

Image review

Done. Thanks for the review. Mike Christie (talk - contribs - library) 11:26, 7 March 2015 (UTC)[reply]
I just saw that one of the paras was pretty short. I don't think all the article sections are summarized yet. I also notice that it is not clearly stated at the start that it can only be used for organic materials - easy to fix. Johnbod (talk) 19:29, 8 March 2015 (UTC)[reply]
I added a sentence about sample form to the shortest lead paragraph. I thought about mentioning the fact that there are separate marine and southern hemisphere calibration curves, but it's hard to do that without any explanation. I think every section is at least represented in the lead. Mike Christie (talk - contribs - library) 20:09, 8 March 2015 (UTC)[reply]
I also added a sentence to the lead explaining the BP notation, and mentioned that the objects to be dated have to be organic. Mike Christie (talk - contribs - library) 11:10, 9 March 2015 (UTC)[reply]
  • In the Principles section, last paragraph: you say these "have not been calibrated", but presumably that just means using Libby's value for the half-life and doesn't refer to the calibrations for variations in historical 14C/12C ratio discussed below?
    It does mean that it has not been calibrated using the historical variation in ratio. Note 2 is intended to clarify this - part (e) is equivalent to saying that there is no calibration. I put it in a note because the definition is a little long to be placed parenthetically, but perhaps I should move it up to a box? As I understand it, the reason to include fractionation in radiocarbon years but not calibration is that calibration curves can vary, and if you want to apply a different calibration curve (e.g. a later INTCAL curve) to data in a paper you're reading, you want the uncalibrated age to apply the curve to. Mike Christie (talk - contribs - library) 11:56, 13 March 2015 (UTC)[reply]
    Sorry, I missed note 2 entirely. Readers who are interested in the details are probably more observant than me, though! Opabinia regalis (talk) 06:10, 14 March 2015 (UTC)[reply]
  • If the PDB standard has an anomalous carbon ratio, how/why did it become the standard of comparison?
    I haven't seen this covered anywhere. I imagine it could be found by chasing a trail of paper references, but Taylor and Bar-Yosef, which is by far the most detailed history, don't even provide a cite for it. I've done some searching (I have JSTOR access) but couldn't find anything. Is this needed for the article? Mike Christie (talk - contribs - library) 11:56, 13 March 2015 (UTC)[reply]
    No, just curious if there was a story behind it :) Opabinia regalis (talk) 06:10, 14 March 2015 (UTC)[reply]
    I found this which indicates that Urey developed the PDB standard as part of his palaeotemperature work on oxygen isotope ratios. Presumably the PDB standard was then adopted for radiocarbon dating because the isotope ratios of the formation were well known. Mike Christie (talk - contribs - library) 20:10, 25 March 2015 (UTC)[reply]
  • You mention the apparent ~400yr age for marine life twice and give an average of 440yrs once, with different citations each time.
    I changed these all to 440, which is much the most recent source, on the assumption that that would be the most accurate. Mike Christie (talk - contribs - library) 02:11, 14 March 2015 (UTC)[reply]
  • "The deepest parts of the ocean mix very slowly with the surface waters, and the mixing is known to be uneven." - I'm usually against the "I never go outside, so I challenge your claim that the sky is blue" types of arguments, but when you use the phrase "known to be" that seems to merit a cite at the end of the sentence (or just delete the phrase).
    I deleted "known to be"; the source definitely supports uneven mixing, so I think that fixes it. Mike Christie (talk - contribs - library) 02:26, 14 March 2015 (UTC)[reply]
  • In measuring the freshwater effect, you write that one usually just measures a modern sample. Does that mean changes in groundwater flow patterns that vary exposure to old-carbon rocks are rare enough to be negligible?
    That's certainly the implication. I looked at a more recent source and was able to find a discussion of this; it's apparent that testing a modern sample is not best practice, so I changed this. Mike Christie (talk - contribs - library) 11:56, 13 March 2015 (UTC)[reply]
  • Hydroxyproline was thought to a reliable indicator of what? I don't quite follow this - it's a major constituent of collagen, but if you have a sample that you know contains collagen, what do you need hydroxyproline to indicate? Is this referring to identifying a sample as collagen-containing in the first place?
    There are problems with dating degraded collagen because it's possible that it could have been contaminated by more recent organic material. One way to confirm that the material you're looking at is original is to verify that the ratios of amino acids are correct; that tells you that you're looking at a sample that is essentially the same composition as the original bone. If hydroxyproline is only found in bone, then separating it and testing only that would be safe because it would eliminate contaminants. I'm thinking that perhaps this should just be cut; since it's been found in groundwater it's no longer that important, and it may be too detailed an issue for this article, which is a summary. Mike Christie (talk - contribs - library) 11:56, 13 March 2015 (UTC)[reply]
    Ah, I see, the modern contaminant is presumably not collagen. "A reliable indicator of purity" or "indicating the absence of modern contamination" or similar would make this clearer, though if it's not a current technique removing it is probably better. (I would not have guessed you'd find hydroxyproline in groundwater, but following the links suggests the type deposited in silica is chemically distinct from the hydroxyproline in animal collagen; this is totally off-topic, but I wonder if they can be distinguished to avoid this problem?) Opabinia regalis (talk) 06:10, 14 March 2015 (UTC)[reply]
    I mentioned this to my archaeologist brother-in-law and he wasn't aware of work along those lines. Might be a research project for someone .... Mike Christie (talk - contribs - library) 20:10, 25 March 2015 (UTC)[reply]
  • HOxII is oxalic acid, right? Any reason not to wikilink this?
    I didn't because it's really the name for the standard, and I thought it might be slightly misleading. I could avoid this by slightly expanding the sentence if you think it's worth it -- e.g. "The most common standard sample material is oxalic acid, such as the HOxII standard..." if you think it's worth it. Mike Christie (talk - contribs - library) 11:56, 13 March 2015 (UTC)[reply]
    IMO the expanded version would be useful. I didn't know what it was, so I googled it and found all kinds of stuff about a particular hox gene.
    That did make me think of another question, though - why oxalic acid as a standard when the test materials are converted to benzene, graphite, etc? Opabinia regalis (talk) 06:10, 14 March 2015 (UTC)[reply]
    I can't find out why oxalic acid was chosen. Taylor and Bar-Yosef say that the original standard was prepared in 1956 at the request of James Arnold, so it was specifically for radiocarbon. I did find this discussion, which mentions that oxalic acid has some disadvantages. I can't find any publications from the NIST (or NBS as it was then) that explain it. Mike Christie (talk - contribs - library) 20:10, 25 March 2015 (UTC)[reply]
    @Opabinia regalis: FYI, I contacted R.E. Taylor, one of the authors of the most recent specialist book on the history of radiocarbon dating, and he said that he believed it was because there's a high oxalic acid content in beet leaves compared to other plants, and Arnold knew the year of growth of the batch of beets that would be tested. Taylor also said he understood the extraction of oxalic acid is straightforward, though he also has heard that the extraction had to be redone because of some errors. Anyway, he's planning to check on these questions the next time he's at UC San Diego and can look at James Arnold's papers. That won't give me a source, of course, but if he puts it in a note I can use that. Mike Christie (talk - contribs - library) 15:37, 29 March 2015 (UTC)[reply]
    Interesting! I guess they had decided on oxalic acid and then went with beets instead of having a convenient pile of beets and going with the easiest chemical. You are going way above and beyond on the investigations here :) Opabinia regalis (talk) 04:25, 30 March 2015 (UTC)[reply]
  • "one archaeologist" - any reason not to name this person? This reads strangely with Taylor prominently mentioned in the same paragraph and quoted in the one before.
    Agreed; I've added his name. Mike Christie (talk - contribs - library) 02:20, 14 March 2015 (UTC)[reply]
  • On the structure question mentioned above: I think the current order of presentation works well, especially since the TOC headings are clear and can direct the reader past the details if they don't want to read everything. My only (subjective, not really actionable) comment here is that the article seems to end abruptly. The last two paragraphs of the Impact section don't seem to connect well to the preceding discussion. I think an example or two of real archaeological data - not pop fluff like the Shroud of Turin - would help bring things together. Maybe the last paragraph could be split into its own subsection.
  • The article is unusually image-depleted, especially with the loss of the Libby portrait. Any thoughts on a replacement lead image? Opabinia regalis (talk) 07:15, 12 March 2015 (UTC)[reply]

Thanks for the review; I should have time this evening to work on these points. One quick note about images: I haven't come up with anything for a lead image; I would love to get a free picture of Libby for the lead, but can't find one. It's not a subject that lends itself well to photographic illustration. If I add a discussion of an archaeological use of radiocarbon dating, as you suggest (and I agree that's a good idea) then perhaps a picture of the dig or location would work. Mike Christie (talk - contribs - library) 12:24, 12 March 2015 (UTC)[reply]

I've added a few comments above but am out of time this morning. I should have a little more time tonight and will do more. I'm away from my sources for a week starting tomorrow, and will probably have very limited access to the internet, so I may not be able to do much more until about 3/22. Mike Christie (talk - contribs - library) 11:56, 13 March 2015 (UTC)[reply]
@Opabinia regalis: I've responded to all but your final point, and in regards to that I think it would be worth giving a more detailed example of a significant real use of the technique in archaeology. Taylor & Bar-Yosef give lots of examples and I'll pick something they highlight. However, I won't be able to do much on this for a week as I'll be skiing in Colorado. I'll have an iPad, but limited internet and none of my references. More when I return. Mike Christie (talk - contribs - library) 02:26, 14 March 2015 (UTC)[reply]
Thanks, looks good - I'll support with an example. No ipads on vacation! :) Opabinia regalis (talk) 06:10, 14 March 2015 (UTC)[reply]
No iPad? You've been talking to my wife. :o) I had time this morning to add one notable application, and I'll do at least one more when I get back. Mike Christie (talk - contribs - library) 12:09, 14 March 2015 (UTC)[reply]
I got packed early and have snuck in one more under the wire. Let me know what you think. Mike Christie (talk - contribs - library) 13:43, 14 March 2015 (UTC)[reply]
Very interesting examples! A question on the first one: I read skimmed both Pleistocene and Holocene and I'm still unclear as to how the boundary was defined in the first place, other than that ice locations are involved - which makes the matter of identifying the date somewhat opaque. Is this possible to clarify briefly?
I don't know about briefly! Here's the explanation -- tell me if this is something you'd like to see in the article. The boundary is defined by tracking the δ18O ratio; that is, the ratio of 16
O
to18
O
. Higher temperatures put more 18
O
in the atmosphere (from evaporation) and so precipitation in warmer times has higher δ18O. Ice cores from Greenland can be used like tree rings to produce a graph of δ18O over time. If you look at page 4 of this book you'll see a graph showing an unmistakable sharp change in climate at 11,650 ± 99 cal BP. That's the Pleistocene-Holocene boundary. Mike Christie (talk - contribs - library) 20:21, 25 March 2015 (UTC)[reply]
Hmm, that is a lot of info - is it too oversimplified to just say this boundary marks a dramatic change in climate and leave it at that? Opabinia regalis (talk) 05:54, 26 March 2015 (UTC)[reply]
I went with『Establishing the date of this boundary − which is defined by sharp climatic warming − as accurately as possible has been a goal of geologists for much of the 20th century.』Mike Christie (talk - contribs - library) 21:00, 26 March 2015 (UTC)[reply]
And a question on the second one: the Dead Sea Scrolls article says they're the second-oldest Bible manuscripts, but also has sections tagged as outdated. Is there a subset of the Dead Sea Scrolls that have previous versions, or is the other article wrong? I'd be tempted to trim the last couple of sentences of the dead sea scrolls paragraph ("some scholars" vs "most scholars" etc...) - it sounds like there's more controversy than can be stuffed into a couple of sentences without losing detail.
I cut the last sentence. That part of the controversy is essentially theological, or at least ideological, and is not really a scientific debate; I put it in as an indication that these measurements don't always settle the issues in everyone's eyes, but I don't think that's really necessary. People can follow the links (or go read the Shroud of Turin article) if they want more details. Mike Christie (talk - contribs - library) 20:52, 25 March 2015 (UTC)[reply]
This could go either way but I think the examples would fit more naturally after the general "impact" section, with maybe the last paragraph split off into a separate section ("other dating methods" or similar?). Not a strong preference though. Have a good vacation! Opabinia regalis (talk) 06:53, 15 March 2015 (UTC)[reply]
I'd like to leave the examples where they are, unless you feel strongly about this. I think one benefit of the examples is that they set up the reader for a better understanding of how dramatic an impact radiocarbon dating can have on an archaeological debate, so having the impact section follow the examples seems right to me. @Opabinia regalis: I think I've now replied to all your comments. Mike Christie (talk - contribs - library) 20:52, 25 March 2015 (UTC)[reply]

Thanks for the ping, read it over again and support, nice work! Opabinia regalis (talk) 05:54, 26 March 2015 (UTC)[reply]

Comments

See my reply above and there are a couple of points you have missed so I have moved them to here:

Further comments

Support. A very fine article on an important subject. Dudley Miles (talk) 09:23, 9 April 2015 (UTC)[reply]

Comments

Perhaps mention this after "once it dies" in Principles (could be a footnote). Non-experts would have a hard time getting this. Nergaal (talk) 23:47, 27 March 2015 (UTC)[reply]
Done; I put this in the atmospheric variation section, which is where the use of tree rings for calibration is discussed. Mike Christie (talk - contribs - library) 16:06, 29 March 2015 (UTC)[reply]
Please add this clarification somewhere in the text. I hat to think really hard to get that this is what the sentence was saying. Nergaal (talk) 23:47, 27 March 2015 (UTC)[reply]
Done, inside the footnote that was already there. Mike Christie (talk - contribs - library) 16:06, 29 March 2015 (UTC)[reply]
then change "this refers" to "however, this actually refers". Nergaal (talk) 23:47, 27 March 2015 (UTC)[reply]
Done -- I just used "actually"; I don't think we need "however" as well. Mike Christie (talk - contribs - library) 16:06, 29 March 2015 (UTC)[reply]

Nergaal (talk) 18:15, 23 March 2015 (UTC)[reply]

@Nergaal: Sorry about the slow replies; I've responded to all your comments above. Mike Christie (talk - contribs - library) 01:55, 26 March 2015 (UTC)[reply]
Put the tree after Intcal_13_calibration_curve.png. Maybe use File:Scintillation counter as a spectrometer.jpg or File:Scintillation Counter.jpg. Nergaal (talk) 21:45, 29 March 2015 (UTC)[reply]
I put the tree at the top of that section and moved the graph down, and trimmed the caption slightly (it was repeating material from the main text). Rather than a scintillation counter I went with an accelerator mass spectrometer, since AMS is now the most important measurement technology. How does it look now? Mike Christie (talk - contribs - library) 22:21, 29 March 2015 (UTC)[reply]

Comments from Freikorp

Source review - spotchecks not done

Both fixed. Thanks for the review. Mike Christie (talk - contribs - library) 17:33, 4 April 2015 (UTC)[reply]

SupportComments. Challenging subject, generally well done.

Great work Mike. hamiltonstone (talk) 12:43, 8 April 2015 (UTC)[reply]

The above discussion is preserved as an archive. Please do not modify it. No further edits should be made to this page.

Retrieved from "https://en.wikipedia.org/w/index.php?title=Wikipedia:Featured_article_candidates/Radiocarbon_dating/archive1&oldid=792599322"





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