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Contents

   



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1 Preparation and structure  





2 References  














Cadmium bromide






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From Wikipedia, the free encyclopedia
 


Cadmium bromide
Cadmium bromide
Names
IUPAC name

Cadmium(II) bromide

Other names

Cadmium dibromide

Identifiers

CAS Number

  • 13464-92-1 (tetrahydrate) checkY
  • 3D model (JSmol)

    ChemSpider
    ECHA InfoCard 100.029.241 Edit this at Wikidata
    EC Number
    • 232-165-1

    PubChem CID

    RTECS number
    • EU9935000
    UNII

    CompTox Dashboard (EPA)

    • InChI=1S/2BrH.Cd/h2*1H;/q;;+2/p-2 checkY

      Key: KPWJBEFBFLRCLH-UHFFFAOYSA-L checkY

    • InChI=1/2BrH.Cd/h2*1H;/q;;+2/p-2

      Key: KPWJBEFBFLRCLH-NUQVWONBAB

    • Br[Cd]Br

    Properties

    Chemical formula

    CdBr2
    Molar mass 272.22 g/mol
    Appearance white solid
    Density 5.192 g/cm3, solid
    Melting point 568 °C (1,054 °F; 841 K)
    Boiling point 844 °C (1,551 °F; 1,117 K)

    Solubility in water

    56.3 g/100 mL (0 °C)
    98.8 g/100 mL (20 °C)
    160 g/100 mL (100 °C)
    Solubility soluble in alcohol, ether, acetone and liquid ammonia.

    Magnetic susceptibility (χ)

    -87.3·10−6cm3/mol
    Structure

    Crystal structure

    Rhombohedral, hr9, SpaceGroup = R-3m, No. 166
    Hazards
    GHS labelling:

    Pictograms

    GHS07: Exclamation markGHS09: Environmental hazard

    Signal word

    Warning

    Hazard statements

    H302, H312, H332, H410

    Precautionary statements

    P220, P273, P280, P501
    NFPA 704 (fire diamond)
    NFPA 704 four-colored diamondHealth 3: Short exposure could cause serious temporary or residual injury. E.g. chlorine gasFlammability 0: Will not burn. E.g. waterInstability 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g. liquid nitrogenSpecial hazards (white): no code
    3
    0
    0
    Lethal dose or concentration (LD, LC):

    LD50 (median dose)

    225 mg/kg, oral (rat)
    NIOSH (US health exposure limits):

    PEL (Permissible)

    [1910.1027] TWA 0.005 mg/m3 (as Cd)[1]

    REL (Recommended)

    Ca[1]

    IDLH (Immediate danger)

    Ca [9 mg/m3 (as Cd)][1]
    Related compounds

    Other anions

    Cadmium chloride,
    Cadmium iodide

    Other cations

    Zinc bromide,
    Calcium bromide,
    Magnesium bromide

    Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

    checkY verify (what is checkY☒N ?)

    Infobox references

    Cadmium bromide is the inorganic compound with the formula CdBr2. It is a white hygroscopic solid. It also can be obtained as a mono- and tetrahydrate.[2] It has few applications.

    Preparation and structure

    [edit]

    Cadmium bromide is prepared by heating cadmium with bromine vapor.[2] The tetrahydrate has been obtained by crystallization of the dibromide from aqueous solution. At 3.04 g/cm3, it is much less dense than the anhydrous material. According to X-ray crystallography, the tetrahydrate is a polymer of CdBr2(H2O)2 with bridging bromide ligands. There are two interstitial water molecules[3]

    References

    [edit]
    1. ^ a b c NIOSH Pocket Guide to Chemical Hazards. "#0087". National Institute for Occupational Safety and Health (NIOSH).
  • ^ a b F. Wagenknecht; R. Juza (1963). "Cadmium bromide". In G. Brauer (ed.). Handbook of Preparative Inorganic Chemistry, 2nd Ed. Vol. 2. NY, NY: Academic Press. p. 1096.
  • ^ Leligny, H.; Monier, J. C. (1978). "Structure Cristalline de CdBr2.4H2O". Acta Crystallographica Section B. 34 (1): 5–8. Bibcode:1978AcCrB..34....5L. doi:10.1107/S0567740878002186.

  • t
  • e

  • Retrieved from "https://en.wikipedia.org/w/index.php?title=Cadmium_bromide&oldid=1229595028"

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    This page was last edited on 17 June 2024, at 17:33 (UTC).

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