| Kutnohorite | |
|---|---|
Kutnohorite, Wessels Mine, Kalahari manganese fields, Northern Cape Province, South Africa. Size 4.4 x 4.2 x 1.9 cm
| |
| General | |
| Category | Carbonate mineral |
| Formula (repeating unit) | CaMn2+(CO3)2 |
| IMA symbol | Kut[1] |
| Strunz classification | 5.AB.10 |
| Dana classification | 14.2.1.3 |
| Crystal system | Trigonal |
| Crystal class | Rhombohedral (3) H-M symbol: (3) |
| Space group | R3 |
| Unit cell | 330.60 ų |
| Identification | |
| Formula mass | 215.0 g/mol (end member) |
| Color | White, pale pink or light brown |
| Crystal habit | Aggregates of bundled bladed crystals |
| Cleavage | Perfect on {1011} |
| Fracture | Subconchoidal |
| Tenacity | Brittle |
| Mohs scale hardness | 3.5–4 |
| Luster | Vitreous to dull |
| Streak | White to pale pink |
| Diaphaneity | Translucent |
| Specific gravity | 3.12 |
| Density | 3.10–3.12 |
| Optical properties | Uniaxial (−) |
| Refractive index | no = 1.710–1.727, ne = 1.519–1.535 |
| Birefringence | 0.191–0.192 |
| Solubility | Soluble in acids |
| References | [2][3][4][5] |
Kutnohorite is a rare calcium manganese carbonate mineral with magnesium and iron that is a member of the dolomite group. It forms a series with dolomite, and with ankerite. The end member formula is CaMn2+(CO3)2,[6] but Mg2+ and Fe2+ commonly substitute for Mn2+, with the manganese content varying from 38% to 84%,[2] so the formula Ca(Mn2+,Mg,Fe2+)(CO3)2 better represents the species. It was named by Professor Bukowsky in 1901 after the type localityofKutná Hora, Bohemia, in the Czech Republic.[7] It was originally spelt "kutnahorite" but "kutnohorite" is the current IMA-approved spelling.
There are three formula units per unit cell (Z = 3) and the lengths of the sides are a close to 4.9 Å and c between 16 Å and 17 Å, although different sources give slightly different values, as follows:
The crystal class is trigonal 3, space groupR3, the same as for the other members of the dolomite group. There are layers of (CO3)(−2 groups perpendicular to the long crystal axis c, and between these layers there are layers of the cations Ca2+ and Mn2+.[2] If there were perfect ordering amongst the cations they would separate into different layers, giving rise to the ordered sequence: Ca−(CO3)−Mn−(CO3)−Ca−(CO3)−Mn−(CO3)− along the c axis;[2] not all specimens, however, display such ordering.[8]
Kutnohorite may be white, pale pink or light brown. The pink shades are due to increased manganese and the brown colours are due to increased iron content. The mineral is translucent with a white to pale pink streak and vitreous to dull luster. It is uniaxial (−) with refractive indicesNo = 1.710 to 1.727 and Ne = 1.519 to 1.535, similar to dolomite. The ordinary refractive index, No, is high, comparable with spinel (1.719).
Kutnohorite occurs as aggregates of bundled blades of white through rose pink to light brown crystals. Also as simple rhombs with curved faces, polycrystalline spherules and in massive and granular habits. It has perfect rhombohedral cleavage, typical of carbonates. It is brittle with a subconchoidal fracture and it is quite soft, with hardness 3.5 to 4, between calcite and fluorite. Specific gravity is 3.12, denser than both dolomite and calcite. It is soluble in acids, as are all carbonates.
Kutnohorite occurs typically in manganiferous sediments, associated with rhodochrosite, aragonite and calcite.[5] Notable occurrences include Tuscany, Italy and Kutná Hora, Czech Republic. It probably occurs at the Trepča Mines, Stari Trg, Kosovo, in the Balkans.[9] At the Eldorado Mine, Ouray County, Colorado, US, it occurs as tiny white crystals partially encrusting quartz and dolomite.[10] At the Ryujima Mine, Nagano Prefecture in Japan, magnesian kutnohorite occurs with quartz and rhodochrosite.[11] The type locality is Poličany, Kutná Hora, Central Bohemia Region, Bohemia, Czech Republic, and type material is conserved at Harvard University, Cambridge, Massachusetts, US.[5]
|
| |||||
|---|---|---|---|---|---|
| Borates |
| ||||
| Carbonates |
| ||||
| Oxides |
| ||||
| Phosphates |
| ||||
| Silicates |
| ||||
| Sulfides |
| ||||
| Other |
| ||||
