Most sandstone is composed of quartzorfeldspar, because they are the most resistant minerals to the weathering processes at the Earth's surface. Like uncemented sand, sandstone may be any color due to impurities within the minerals, but the most common colors are tan, brown, yellow, red, grey, pink, white, and black. Because sandstone beds can form highly visible cliffs and other topographic features, certain colors of sandstone have become strongly identified with certain regions, such as the red rock deserts of Arches National Park and other areas of the American Southwest.
Rock formations composed of sandstone usually allow the percolation of water and other fluids and are porous enough to store large quantities, making them valuable aquifers and petroleum reservoirs.[2][3]
As sediments continue to accumulate in the depositional environment, older sand is buried by younger sediments, and it undergoes diagenesis. This mostly consists of compaction and lithification of the sand.[10][11] Early stages of diagenesis, described as eogenesis, take place at shallow depths (a few tens of meters) and are characterized by bioturbation and mineralogical changes in the sands, with only slight compaction.[12] The red hematite that gives red bed sandstones their color is likely formed during eogenesis.[13][14] Deeper burial is accompanied by mesogenesis, during which most of the compaction and lithification takes place.[11]
Compaction takes place as the sand comes under increasing pressure from overlying sediments. Sediment grains move into more compact arrangements, ductile grains (such as mica grains) are deformed, and pore space is reduced. In addition to this physical compaction, chemical compaction may take place via pressure solution. Points of contact between grains are under the greatest strain, and the strained mineral is more soluble than the rest of the grain. As a result, the contact points are dissolved away, allowing the grains to come into closer contact.[11]
Lithification follows closely on compaction, as increased temperatures at depth hasten deposition of cement that binds the grains together. Pressure solution contributes to cementing, as the mineral dissolved from strained contact points is redeposited in the unstrained pore spaces.[11]
Mechanical compaction takes place primarily at depths less than 1,000 meters (3,300 ft). Chemical compaction continues to depths of 2,000 meters (6,600 ft), and most cementation takes place at depths of 2,000–5,000 meters (6,600–16,400 ft).[15]
Unroofing of buried sandstone is accompanied by telogenesis, the third and final stage of diagenesis.[12] As erosion reduces the depth of burial, renewed exposure to meteoric water produces additional changes to the sandstone, such as dissolution of some of the cement to produce secondary porosity.[11]
Paradise Quarry, Sydney, AustraliaGrus sand and the granitoid from which it is derived
Framework grains are sand-sized (0.0625-to-2-millimeter (0.00246 to 0.07874 in) diameter) detrital fragments that make up the bulk of a sandstone.[16][17] Most framework grains are composed of quartzorfeldspar, which are the common minerals most resistant to weathering processes at the Earth's surface, as seen in the Goldich dissolution series.[18] Framework grains can be classified into several different categories based on their mineral composition:
Quartz framework grains are the dominant minerals in most clastic sedimentary rocks; this is because they have exceptional physical properties, such as hardness and chemical stability.[1] These physical properties allow the quartz grains to survive multiple recycling events, while also allowing the grains to display some degree of rounding.[1] Quartz grains evolve from plutonic rock, which are felsic in origin and also from older sandstones that have been recycled.
Feldspathic framework grains are commonly the second most abundant mineral in sandstones.[1] Feldspar can be divided into alkali feldspars and plagioclase feldspars, which can be distinguished under a petrographic microscope.[1]
Alkali feldspar range in chemical composition from KAlSi3O8 to NaAlSi3O8.[1]
Photomicrograph of a volcanic sand grain; upper picture is plane-polarised light, bottom picture is cross-polarised light, scale box at left-centre is 0.25 millimeter. This type of grain would be a main component of a lithic sandstone.
Lithic framework grains (also called lithic fragments or lithic clasts) are pieces of ancient source rock that have yet to weather away to individual mineral grains.[1] Lithic fragments can be any fine-grained or coarse-grained igneous, metamorphic, or sedimentary rock,[1] although the most common lithic fragments found in sedimentary rocks are clasts of volcanic rocks.[1]
Accessory minerals are all other mineral grains in a sandstone. These minerals usually make up just a small percentage of the grains in a sandstone. Common accessory minerals include micas (muscovite and biotite), olivine, pyroxene, and corundum.[1][19] Many of these accessory grains are more dense than the silicates that make up the bulk of the rock. These heavy minerals are commonly resistant to weathering and can be used as an indicator of sandstone maturity through the ZTR index.[20] Common heavy minerals include zircon, tourmaline, rutile (hence ZTR), garnet, magnetite, or other dense, resistant minerals derived from the source rock.
Matrix is very fine material, which is present within interstitial pore space between the framework grains.[1] The nature of the matrix within the interstitial pore space results in a twofold classification:
Arenites are texturally clean sandstones that are free of or have very little matrix.[19]
Wackes are texturally dirty sandstones that have a significant amount of matrix.[17]
Cement is what binds the siliciclastic framework grains together. Cement is a secondary mineral that forms after deposition and during burial of the sandstone.[1] These cementing materials may be either silicate minerals or non-silicate minerals, such as calcite.[1]
Silica cement can consist of either quartz or opal minerals. Quartz is the most common silicate mineral that acts as cement. In sandstone where there is silica cement present, the quartz grains are attached to cement, which creates a rim around the quartz grain called overgrowth. The overgrowth retains the same crystallographic continuity of quartz framework grain that is being cemented. Opal cement is found in sandstones that are rich in volcanogenic materials, and very rarely is in other sandstones.[1]
Calcite cement is the most common carbonate cement. Calcite cement is an assortment of smaller calcite crystals. The cement adheres to the framework grains, cementing the framework grains together.[1]
Sandstone that becomes depleted of its cement binder through weathering gradually becomes friable and unstable. This process can be somewhat reversed by the application of tetraethyl orthosilicate (Si(OC2H5)4) which will deposit amorphous silicon dioxide between the sand grains.[21] The reaction is as follows.
Pore space includes the open spaces within a rock or a soil.[22] The pore space in a rock has a direct relationship to the porosity and permeability of the rock. The porosity and permeability are directly influenced by the way the sand grains are packed together.[1]
Porosity is the percentage of bulk volume that is inhabited by interstices within a given rock.[22] Porosity is directly influenced by the packing of even-sized spherical grains, rearranged from loosely packed to tightest packed in sandstones.[1]
Permeability is the rate in which water or other fluids flow through the rock. For groundwater, work permeability may be measured in gallons per day through a one square foot cross section under a unit hydraulic gradient.[22]
Sandstones are typically classified by point-counting a thin section using a method like the Gazzi-Dickinson Method. This yields the relative percentages of quartz, feldspar, and lithic grains and the amount of clay matrix. The composition of a sandstone can provide important information on the genesis of the sediments when used with a triangular Quartz, Feldspar, Lithic fragment (QFL diagrams). However, geologist have not been able to agree on a set of boundaries separating regions of the QFL triangle.[1]
Ternary plot showing the relative abundance of quartz, feldspar, and lithic grains in a sandstone
Visual aids are diagrams that allow geologists to interpret different characteristics of a sandstone. For example, a QFL chart can be marked with a provenance model that shows the likely tectonic origin of sandstones with various compositions of framework grains. Likewise, the stage of textural maturity chart illustrates the different stages that a sandstone goes through as the degree of kinetic processing of the sediments increases.[23]
Schematic QFL diagram showing tectonic provinces and sandstone provenance
A QFL chart is a representation of the framework grains and matrix that is present in a sandstone. This chart is similar to those used in igneous petrology. When plotted correctly, this model of analysis creates for a meaningful quantitative classification of sandstones.[24]
A sandstone provenance chart is typically based on a QFL chart but allows geologists to visually interpret the different types of places from which sandstones can originate.
A stage of textural maturity chart shows the differences between immature, submature, mature, and supermature sandstones. As the sandstone becomes more mature, grains become more rounded, and there is less clay in the matrix of the rock.[1]
Diagram showing a slightly modified version of the Dott (1964) classification scheme
Dott's (1964) sandstone classification scheme is one of many such schemes used by geologists for classifying sandstones. Dott's scheme is a modification of Gilbert's classification of silicate sandstones, and it incorporates R.L. Folk's dual textural and compositional maturity concepts into one classification system.[25] The philosophy behind combining Gilbert's and R. L. Folk's schemes is that it is better able to "portray the continuous nature of textural variation from mudstone to arenite and from stable to unstable grain composition".[25] Dott's classification scheme is based on the mineralogy of framework grains, and on the type of matrix present in between the framework grains.[citation needed]
In this specific classification scheme, Dott has set the boundary between arenite and wackes at 15% matrix. In addition, Dott also breaks up the different types of framework grains that can be present in a sandstone into three major categories: quartz, feldspar, and lithic grains.[1]
Arenites are types of sandstone that have less than 15% clay matrix in between the framework grains.
Quartz arenites are sandstones that contain more than 90% of siliceous grains. Grains can include quartzorchert rock fragments.[1] Quartz arenites are texturally mature to supermature sandstones. These pure quartz sands result from extensive weathering that occurred before and during transport. This weathering removed everything but quartz grains, the most stable mineral. They are commonly affiliated with rocks that are deposited in a stable cratonic environment, such as aeolian beaches or shelf environments.[1] Quartz arenites emanate from multiple recycling of quartz grains, generally as sedimentary source rocks and less regularly as first-cycle deposits derived from primary igneousormetamorphic rocks.[1]
Feldspathic arenites are sandstones that contain less than 90% quartz, and more feldspar than unstable lithic fragments, and minor accessory minerals.[1] Feldspathic sandstones are commonly immature or sub-mature.[1] These sandstones occur in association with cratonic or stable shelf settings.[1] Feldspathic sandstones are derived from granitic-type, primary crystalline, rocks.[1] If the sandstone is dominantly plagioclase, then it is igneous in origin.[1]
Lithic arenites are characterised by generally high content of unstable lithic fragments. Examples include volcanic and metamorphic clasts, though stable clasts such as chert are common in lithic arenites.[1] This type of rock contains less than 90% quartz grains and more unstable rock fragments than feldspars.[1] They are commonly immature to submature texturally.[1] They are associated with fluvial conglomerates and other fluvial deposits, or in deeper water marine conglomerates.[1] They are formed under conditions that produce large volumes of unstable material, derived from fine-grained rocks, mostly shales, volcanic rocks, and metamorphic rock.[1]
Wackes are sandstones that contain more than 15% clay matrix between framework grains.
Quartz wackes are uncommon because quartz arenites are texturally mature to supermature.[1]
Felspathic wackes are feldspathic sandstone that contain a matrix that is greater than 15%.[1]
Lithic wacke is a sandstone in which the matrix greater than 15%.[1]
Greywacke sandstones are a heterogeneous mixture of lithic fragments and angular grains of quartz and feldspar or grains surrounded by a fine-grained clay matrix. Much of this matrix is formed by relatively soft fragments, such as shale and some volcanic rocks, that are chemically altered and physically compacted after deep burial of the sandstone formation.
When sandstone is subjected to the great heat and pressure associated with regional metamorphism, the individual quartz grains recrystallize, along with the former cementing material, to form the metamorphic rock called quartzite. Most or all of the original texture and sedimentary structures of the sandstone are erased by the metamorphism.[4] The grains are so tightly interlocked that when the rock is broken, it fractures through the grains to form an irregular or conchoidal fracture.[26]
Geologists had recognized by 1941 that some rocks show the macroscopic characteristics of quartzite, even though they have not undergone metamorphism at high pressure and temperature. These rocks have been subject only to the much lower temperatures and pressures associated with diagenesis of sedimentary rock, but diagenesis has cemented the rock so thoroughly that microscopic examination is necessary to distinguish it from metamorphic quartzite. The term orthoquartzite is used to distinguish such sedimentary rock from metaquartzite produced by metamorphism. By extension, the term orthoquartzite has occasionally been more generally applied to any quartz-cemented quartz arenite. Orthoquartzite (in the narrow sense) is often 99% SiO2 with only very minor amounts of iron oxide and trace resistant minerals such as zircon, rutile and magnetite. Although few fossils are normally present, the original texture and sedimentary structures are preserved.[27][28]
The typical distinction between a true orthoquartzite and an ordinary quartz sandstone is that an orthoquartzite is so highly cemented that it will fracture across grains, not around them.[29] This is a distinction that can be recognized in the field. In turn, the distinction between an orthoquartzite and a metaquartzite is the onset of recrystallization of existing grains. The dividing line may be placed at the point where strained quartz grains begin to be replaced by new, unstrained, small quartz grains, producing a mortar texture that can be identified in thin sections under a polarizing microscope. With increasing grade of metamorphism, further recrystallization produces foam texture, characterized by polygonal grains meeting at triple junctions, and then porphyroblastic texture, characterized by coarse, irregular grains, including some larger grains (porphyroblasts.)[26]
Sandstone has been used since prehistoric times for construction,[30][31] decorative art works[32] and tools.[33] It has been widely employed around the world in constructing temples,[34] churches,[34] homes and other buildings, and in civil engineering.[35]
Although its resistance to weathering varies, sandstone is easy to work. That makes it a common building and paving material, including in asphalt concrete. However, some types that have been used in the past, such as the Collyhurst sandstone used in North West England, have had poor long-term weather resistance, necessitating repair and replacement in older buildings.[36] Because of the hardness of individual grains, uniformity of grain size and friability of their structure, some types of sandstone are excellent materials from which to make grindstones, for sharpening blades and other implements.[37] Non-friable sandstone can be used to make grindstones for grinding grain, e.g., gritstone.
A type of pure quartz sandstone, orthoquartzite, with more of 90–95 percent of quartz,[38] has been proposed for nomination to the Global Heritage Stone Resource.[39] In some regions of Argentina, the orthoquartzite-stoned facade is one of the main features of the Mar del Plata style bungalows.[39]
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^ abMarshak, Stephen. Essentials of Geology (3rd ed.). p. 182.
^Powell, Darryl. "Quartzite". Mineral Information Institute. Archived from the original on 2009-03-02. Retrieved 2009-09-09.
^ ab"A Basic Sedimentary Rock Classification", L.S. Fichter, Department of Geology/Environmental Science, James Madison University (JMU), Harrisonburg, Virginia, October 2000, JMU-sed-classifArchived 2011-07-23 at the Wayback Machine (accessed: March 2009): separates clastic, chemical & biochemical (organic).
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^Blatt, Harvey; Tracy, Robert J. (1996). Petrology : igneous, sedimentary, and metamorphic (2nd ed.). New York: W.H. Freeman. pp. 241–242, 258–260. ISBN0716724383.
^Prothero & Schwab, Donald R. & Fred (1996). Sedimentary Geology. W. H. Freeman. p. 24. ISBN0-7167-2726-9.
^ abProthero, D. (2004). Sedimentary Geology. New York, NN: W.H. Freeman and Company
^Prothero, D. R. and Schwab, F., 1996, Sedimentary Geology, p. 460, ISBN0-7167-2726-9
^Zárraga, Ramón; Alvarez-Gasca, Dolores E.; Cervantes, Jorge (1 September 2002). "Solvent effect on TEOS film formation in the sandstone consolidation process". Silicon Chemistry. 1 (5): 397–402. doi:10.1023/B:SILC.0000025602.64965.e7. S2CID93736643.
^ abcJackson, J. (1997). Glossary of Geology. Alexandria, VA: American Geological Institute ISBN3-540-27951-2
^Allaby, Michael (2013). A dictionary of geology and earth sciences (Fourth ed.). Oxford: Oxford University Press. ISBN9780199653065.
^Jackson, Julia A., ed. (1997). Glossary of geology (Fourth ed.). Alexandria, Virginia: American Geological Institute. p. 525. ISBN0922152349.
^Applegate, Alex; Zedeño, Nieves (2001). "Site E-92-8: A Late Prehistoric C-Group Component at Nabta Playa". Holocene Settlement of the Egyptian Sahara. pp. 529–533. doi:10.1007/978-1-4615-0653-9_19. ISBN978-1-4613-5178-8.
^ abSaleh, Saleh A.; Helmi, Fatma M.; Kamal, Monir M.; E. El-Banna-a1, Abdel-Fattah (May 1992). "Study and consolidation of sandstone: Temple of Karnak, Luxor, Egypt". Studies in Conservation. 37 (2): 93–104. doi:10.1179/sic.1992.37.2.93.{{cite journal}}: CS1 maint: numeric names: authors list (link)
^Grissom, Carol A.; Aloiz, Emily M.; Vicenzi, Edward P.; Livingston, Richard A. (2020). "Seneca sandstone: a heritage stone from the USA". Geological Society, London, Special Publications. 486 (1): 163–176. Bibcode:2020GSLSP.486..163G. doi:10.1144/SP486.4. S2CID134230768.
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Scholle, P.A., and D. Spearing, 1982, Sandstone depositional environments: clastic terrigenous sediments , American Association of Petroleum Geologists Memoir no. 31. ISBN0-89181-307-1.
