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The first reaction does not make sense. hydrogen cyanate is a weak acid, pKa = 3.7, whereas the ammonium ion has a pKa of 9.25 (presumably at 25C). Therefore it is unlikely be quantitative, as implied by the -> sign. Overall, two hydrogen atoms are removed from the ammonium group which is clearly not an acid-base reaction. It is a multistage reaction so the sign is not appropriate. Temperature and pH should be stated. Replace by
?Petergans (talk) 11:53, 31 July 2020 (UTC)[reply]