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A closed fullerene with sphere-like shell must have at least some cycles that are pentagons or heptagons. More precisely, if all the faces have 5 or 6 sides, it follows from [[Euler characteristic|Euler's polyhedron formula]], ''V''−''E''+''F''=2 (where ''V'', ''E'', ''F'' are the numbers of vertices, edges, and faces), that ''V'' must be even, and that there must be exactly 12 pentagons and ''V''/2−10 hexagons. Similar constraints exist if the fullerene has heptagonal (seven-atom) cycles.<ref>[https://www.britannica.com/EBchecked/topic/221916/fullerene "Fullerene"], ''Encyclopædia Britannica'' on-line</ref>

A closed fullerene with sphere-like shell must have at least some cycles that are pentagons or heptagons. More precisely, if all the faces have 5 or 6 sides, it follows from [[Euler characteristic|Euler's polyhedron formula]], ''V''−''E''+''F''=2 (where ''V'', ''E'', ''F'' are the numbers of vertices, edges, and faces), that ''V'' must be even, and that there must be exactly 12 pentagons and ''V''/2−10 hexagons. Similar constraints exist if the fullerene has heptagonal (seven-atom) cycles.<ref>[https://www.britannica.com/EBchecked/topic/221916/fullerene "Fullerene"], ''Encyclopædia Britannica'' on-line</ref>


Open fullerenes, like carbon nanotubes and graphene, can consist entirely of hexagonal rings. In theory, a long nanotube with ends joined to form a closed [[torus]]-like sheet could also consist entirely of hexagons.



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