Jump to content
 







Main menu
   


Navigation  



Main page
Contents
Current events
Random article
About Wikipedia
Contact us
Donate
 




Contribute  



Help
Learn to edit
Community portal
Recent changes
Upload file
 








Search  

































Create account

Log in
 









Create account
 Log in
 




Pages for logged out editors learn more  



Contributions
Talk
 



















Contents

   



(Top)
 


1 References  














Iron phosphide






Српски / srpski
Srpskohrvatski / српскохрватски
ி

 

Edit links
 









Article
Talk
 

















Read
Edit
View history
 








Tools
   


Actions  



Read
Edit
View history
 




General  



What links here
Related changes
Upload file
Special pages
Permanent link
Page information
Cite this page
Get shortened URL
Download QR code
Wikidata item
 




Print/export  



Download as PDF
Printable version
 
















Appearance
   

 






From Wikipedia, the free encyclopedia
 


Iron phosphide
Identifiers

CAS Number

3D model (JSmol)

PubChem CID

CompTox Dashboard (EPA)

  • InChI=1S/3Fe.H3P/h;;;1H3

  • [Fe]#P

Properties

Chemical formula

FeP
Molar mass 86.819 g·mol−1
Density 6.74 g/cm3
Melting point 1,100 °C (2,010 °F; 1,370 K)

Solubility in water

Insoluble in water
Solubility soluble in nitric acid, HF, aqua regia
insoluble in dilute acid, alkalis
Structure[1]

Crystal structure

MnP type (Orthorhombic)

Space group

Pnma (No. 62)

Lattice constant

a = 519.1 pm, b = 309.9 pm, c = 579.2 pm

Lattice volume (V)

93.2 Å3
Related compounds

Other cations

Chromium phosphide
Manganese phosphide
Cobalt phosphide
Tungsten phosphide
Ruthenium phosphide

Related compounds

Fe2P; Fe3P

Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

☒N verify (what is checkY☒N ?)

Infobox references

Iron phosphide is a chemical compound of iron and phosphorus, with a formula of FeP.<[1] Its physical appearance is grey needles.

Manufacturing of iron phosphide takes place at elevated temperatures, where the elements combine directly.[1] Iron phosphide reacts with moisture and acids producing phosphine (PH3), a toxic and pyrophoric gas.

Iron phosphide is a good electric and heat conductor.[2]

Below a Néel temperature of about 119 K, FeP takes on an helimagnetic structure.[3]

References[edit]

  1. ^ a b c Rundqvist, Stig; Sillén, Lars Gunnar; Timm, D.; Motzfeldt, K.; Theander, Olof; Flood, H. (1962). "Phosphides of the B31 (MnP) Structure Type". Acta Chemica Scandinavica. 16. Danish Chemical Society: 287–292. doi:10.3891/acta.chem.scand.16-0287. ISSN 0904-213X.
  • ^ Vereshchagin, Oleg S.; Pankin, Dmitrii V.; Smirnov, Mikhail B.; Vlasenko, Natalia S.; Shilovskikh, Vladimir V.; Britvin, Sergey N. (February 2021). "Raman spectroscopy: A promising tool for the characterization of transition metal phosphides". Journal of Alloys and Compounds. 853: 156468. doi:10.1016/j.jallcom.2020.156468.
  • ^ Chernyavskii, I. O.; Nikitin, S. E.; Onykiienko, Y. A.; Inosov, D. S.; Stahl, Q.; et al. (2020-08-24). "Incommensurate magnet iron monophosphide FeP: Crystal growth and characterization". Physical Review Materials. 4 (8). American Physical Society (APS): 083403. arXiv:2003.10968. Bibcode:2020PhRvM...4h3403C. doi:10.1103/physrevmaterials.4.083403. ISSN 2475-9953. S2CID 214623160.

  • Retrieved from "https://en.wikipedia.org/w/index.php?title=Iron_phosphide&oldid=1226211030"

    Categories: 
    Phosphorus compounds
    Iron compounds
    Phosphides
    Semiconductor materials
    Hidden categories: 
    Articles with short description
    Short description matches Wikidata
    Chemical pages without ChemSpiderID
    Articles without EBI source
    Articles without KEGG source
    Articles without UNII source
    Articles containing unverified chemical infoboxes
    Chembox articles without image
     



    This page was last edited on 29 May 2024, at 06:41 (UTC).

    Text is available under the Creative Commons Attribution-ShareAlike License 4.0; additional terms may apply. By using this site, you agree to the Terms of Use and Privacy Policy. Wikipedia® is a registered trademark of the Wikimedia Foundation, Inc., a non-profit organization.



    Privacy policy

    About Wikipedia

    Disclaimers

    Contact Wikipedia

    Code of Conduct

    Developers

    Statistics

    Cookie statement

    Mobile view



    Wikimedia Foundation
    Powered by MediaWiki