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Contents

   



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1 Synthesis  




2 Physical properties  




3 References  













Praseodymium monophosphide






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From Wikipedia, the free encyclopedia
  
(Redirected from Praseodymium phosphide)
"Praseodymium phosphide" redirects here. For the pentaphosphide, see Praseodymium pentaphosphide.
Praseodymium monophosphide
Names
Other names

Phosphanylidynepraseodymium

Identifiers

CAS Number

3D model (JSmol)
ChemSpider
ECHA InfoCard 100.031.868 Edit this at Wikidata
EC Number
  • 235-068-2

PubChem CID

CompTox Dashboard (EPA)

  • InChI=1S/P.Pr

    Key: ZWIUVBLJANXBMO-UHFFFAOYSA-N

  • P#[Pr]

Properties

Chemical formula

 PPr
Molar mass 171.88142 g·mol−1
Appearance Dark green crystals[1]

Solubility in water

 Decomposes in water
Structure

Crystal structure

 cubic
Related compounds

Other anions

 Praseodymium nitride
Praseodymium arsenide
Praseodymium antimonide
Praseodymium bismuthide

Other cations

 Cerium phosphide
Neodymium phosphide

Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Infobox references

Praseodymium monophosphide is an inorganic compoundofpraseodymium and phosphorus with the chemical formula PrP.[2][3][4] The compound forms crystals.

Synthesis

[edit]

Praseoymium monophosphide can be prepared by heating praseodymium and phosphorus in the presence of iodine vapor:[5]

Physical properties

[edit]

Praseodymium monophosphide forms crystals of a cubic system, space group Fm3m, with cell parameters a = 0.5872 nm, Z = 4, and structure like sodium chloride NaCl.[6][7] It melts congruently at 3120 °C.

References

[edit]
  1. ^ Rowley, Adrian T.; Parkin, Ivan P. (1993). "Convenient synthesis of lanthanide and mixed lanthanide phosphides by solid-state routes involving sodium phosphide". Journal of Materials Chemistry. 3 (7). Royal Society of Chemistry (RSC): 689. doi:10.1039/jm9930300689. ISSN 0959-9428.
  • ^ "Praseodymium Phosphide". American Elements. Retrieved 14 December 2021.
  • ^ Toxic Substances Control Act (TSCA) Chemical Substance Inventory. Cumulative Supplement to the Initial Inventory: User Guide and Indices. United States Environmental Protection Agency. 1980. p. 252. Retrieved 14 December 2021.
  • ^ O'Bannon, Loran (6 December 2012). Dictionary of Ceramic Science and Engineering. Springer Science & Business Media. p. 199. ISBN 978-1-4613-2655-7. Retrieved 14 December 2021.
  • ^ Mironov, K. E. (1 January 1968). "A transport reaction for the growth of praseodymium phospide". Journal of Crystal Growth. 3–4: 150–152. Bibcode:1968JCrGr...3..150M. doi:10.1016/0022-0248(68)90115-2. Retrieved 14 December 2021.
  • ^ Nowacki, J. D. H. Donnay, and Werner (1954). Crystal Data: Classification of Substances by Space Groups and their Identification from Cell Dimensions. Geological Society of America. p. 509. ISBN 978-0-8137-1060-0. Retrieved 14 December 2021.{{cite book}}: CS1 maint: multiple names: authors list (link)
  • ^ Yaduvanshi, Namrata; Singh, Sadhna (10 April 2018). Exploration of pressure induced phase transition in praseodymium phosphide (PrP) with the NaCl-type structure. Dae Solid State Physics Symposium 2017. AIP Conference Proceedings. Vol. 1942. p. 030001. Bibcode:2018AIPC.1942c0001Y. doi:10.1063/1.5028582. Retrieved 14 December 2021.

    • Retrieved from "https://en.wikipedia.org/w/index.php?title=Praseodymium_monophosphide&oldid=1214244807"
    Categories: 
    ●Phosphides
     ●Praseodymium(III) compounds
     ●Rock salt crystal structure
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