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Contents

   



(Top)
 


1 Preparation  





2 Chemical properties  





3 References  














Praseodymium(III) perchlorate






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From Wikipedia, the free encyclopedia
 


Praseodymium perchlorate
Structure of praseodymium perchlorate
Identifiers

CAS Number

3D model (JSmol)

ChemSpider
ECHA InfoCard 100.033.460 Edit this at Wikidata
EC Number

PubChem CID

UN number 3098[2]
  • InChI=1S/3ClHO4.Pr/c3*2-1(3,4)5;/h3*(H,2,3,4,5);/q;;;+3/p-3[1]

    Key: OPAITELCMCAYEB-UHFFFAOYSA-K

  • [O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O.[Pr+3]

Properties

Chemical formula

Pr(ClO4)3
Molar mass 439.259[1]
Density 1.563[2]
Melting point liquid at room temperature[2]
Vapor pressure 0.21 psi (20 °C)[2]

Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Infobox references

Praseodymium(III) perchlorate is the perchlorate salt of praseodymium, with the chemical formula of Pr(ClO4)3.[3]

Preparation[edit]

Praseodymium(III) perchlorate can be prepared from praseodymium(III,IV) oxide.[4][5] Dissolving praseodymium(III,IV) oxide in a slight excess of hydrochloric acid and adding a small amount of hydrogen peroxide can prepare praseodymium perchlorate.[5]

Chemical properties[edit]

Praseodymium perchlorate can form two complexes with crown ether 18-crown-6instoichiometric ratios of 1:1 and 1:2.,[6] and can form complexes with L-proline,[7] glutamic acid,[4] mandelic acid,[4] penicillamine.[4] It can also form complexes with imidazole and alanine.[5]

References[edit]

  1. ^ a b c "Praseodymium perchlorate". ChemSpider. Retrieved 2017-10-21.
  • ^ a b c d e "Praseodymium perchlorate 13498-07-2". www.chemicalbook.com. Retrieved 2017-10-20.
  • ^ PubChem. "Praseodymium(3+) perchlorate". pubchem.ncbi.nlm.nih.gov. Retrieved 2022-07-11.
  • ^ a b c d 张若桦, 陈敬堂、江冬青 (1995). "镨(III)溶液光谱研究:高氯酸镨─谷氨酸/苦杏仁酸/青霉胺配合物". Acta Scientiarum Naturalium Universitatis Nankaiensis (1): 44-48. ISSN 0465-7942. Retrieved 2017-10-21.
  • ^ a b c 但悠梦, 胡卫兵、余华光、董家新、刘义、屈松生 (2006). "稀土配合物[Pr(C3H7NO2)2(C3H4N2)(H2O)](ClO4)3的标准生成焓及热分解动力学研究" [Standard Molar Enthalpy of Formation and Thermal Decomposition Kinetic Study of Rare Earth Complex [Pr(C3H7NO2)2(C3H4N2)(H2O)](ClO4)3]. Acta Chimica Sinica. 64 (1): 70-78. doi:10.3321/j.issn:0567-7351.2006.01.012. ISSN 0567-7351. S2CID 236111702. Retrieved 2017-10-21.
  • ^ Xue Ganglin; Li Qianding; Hu Shaoming; Xu Hong; Ren Dehou; Zhuang Quanzhen (1996). "三水合高氯酸镨与18—冠—6配合物的研究" [Study on complexes of trihydrated praseodymium perchlorate with 18 -crown-6]. Acta Chimica Sinica (in Chinese). 54 (6): 568-574. ISSN 0567-7351. Retrieved 2017-10-14.
  • ^ 张忠海, 姜晓娟, 库宗军. 高氯酸镨与L-脯氨酸配合物的合成及热化学和热分解动力学研究[C]// 中国化学会全国化学热力学和热分析学术会议. 2006.

  • Retrieved from "https://en.wikipedia.org/w/index.php?title=Praseodymium(III)_perchlorate&oldid=1193591171"

    Categories: 
    Praseodymium(III) compounds
    Perchlorates
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