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Contents

   



(Top)
 


1 Preparation  





2 Physical properties  





3 See also  





4 References  














Praseodymium bismuthide






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Praseodymium bismuthide
Names
Other names

Praseodymium(III) bismuthide
Bismuth-Praseodymium

Identifiers

3D model (JSmol)

  • InChI=1S/Bi.Pr

    Key: GXEWOMCEINAZJT-UHFFFAOYSA-N

  • [Pr].[Bi]

Properties

Chemical formula

BiPr
Molar mass 349.89 g/mol
Density 8.6 g/cm3
Melting point 1800 °C
Critical point (T, P) -111 kJ/mol[1]
Structure

Crystal structure

cubic

Space group

Fm3m
Related compounds

Other anions

PrN, PrP, PrAs, PrSb, Pr2O3

Other cations

CeBi, NdBi

Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Infobox references

Praseodymium bismuthide is a binary inorganic compound of praseodymium and bismuth with the chemical formula of PrBi. It forms crystals.

Preparation

[edit]

Praseodymium bismuthide can be prepared by reacting stoichiometric amounts of praseodymium and bismuth at 1800 °C:[citation needed]

Physical properties

[edit]

Praseodymium bismuthide forms crystals of the cubic crystal system, with space group Fm3m, cell parameters a = 0.64631 nm, Z = 4, and a structure like sodium chloride NaCl.[2][3][4] The compound melts congruently at a temperature of roughly 1800 °С.[5][6] At a pressure of 14 GPa, it undergoes a phase transition.[7]

See also

[edit]

References

[edit]
  1. ^ A. Borsese; R. Capelli; S. Delfino; R. Ferro (1974). "The heat of formation of neodymium-bismuth alloys". Thermochimica Acta. 8 (4): 393–397. doi:10.1016/0040-6031(74)85107-5.
  • ^ Диаграммы состояния двойных металлических систем. Vol. 1. М.: Машиностроение. 1996. ISBN 5-217-02688-X. {{cite book}}: Unknown parameter |agency= ignored (help)
  • ^ K. A. Gschneidner, F. W. Calderwood (1989). "The Bi−Pr (Bismuth-Praseodymium) system". Bulletin of Alloy Phase Diagrams. 10 (4) (Bulletin of Alloy Phase Diagrams ed.): 447–450. doi:10.1007/BF02882373.
  • ^ B. Predel (1992). "Bi-Pr (Bismuth-Praseodymium)". B-Ba – C-Zr. Landolt-Börnstein - Group IV Physical Chemistry. Vol. 5b (Landolt-Börnstein - Group IV Physical Chemistry ed.). pp. 1–3. doi:10.1007/10040476_575. ISBN 3-540-55115-8.
  • ^ Y. Castrillejo, M.R. Bermejo, P. Dı´az Arocas, A.M. Martı´nez, E. Barrado (2005). "The electrochemical behaviour of the Pr(III)/Pr redox system at Bi and Cd liquid electrodes in molten eutectic LiCl–KCl". Journal of Electroanalytical Chemistry. 579 (2) (Journal of Electroanalytical Chemistry ed.): 343–358. doi:10.1016/j.jelechem.2005.03.001.{{cite journal}}: CS1 maint: multiple names: authors list (link)
  • ^ K.A. Gschneidner Jr., F.W. Calderwood, T.B. Massalski (1990). Binary alloy phase diagrams. ASM International. pp. 776–1015.{{cite book}}: CS1 maint: multiple names: authors list (link)
  • ^ Shirotani Ichimin, Hayashi Junichi, Yamanashi Keigo, Hirano Kouji, Adachi Takafumi, Ishimatsu Naoki, Shimomura Osamu, Kikegawa Takumi (2003). "X-ray study with synchrotron radiation of cerium and praseodymium monopnictides with the NaCl-type structure at high pressures". Physica B: Condensed Matter. 334 (1–2) (Physica B: Physics of Condensed Matter ed.): 167–174. Bibcode:2003PhyB..334..167S. doi:10.1016/S0921-4526(03)00042-5.{{cite journal}}: CS1 maint: multiple names: authors list (link)

  • Retrieved from "https://en.wikipedia.org/w/index.php?title=Praseodymium_bismuthide&oldid=1208982878"

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