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Stannocene






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From Wikipedia, the free encyclopedia
  

Stannocene
Names
IUPAC name
  • Stannocene
  • Bis(η5-cyclopentadienyl)tin(II)
    • Other names
    • Bis(cyclopentadienyl)tin
  • Di(cyclopentadienyl)tin
    • Identifiers

    CAS Number

    3D model (JSmol)

    • InChI=1S/2C5H5.Sn/c2*1-2-4-5-3-1;/h2*1-5H;/q2*-1;+2

      Key: CRQFNSCGLAXRLM-UHFFFAOYSA-N

    • [cH-]1cccc1.[cH-]1cccc1.[Sn+2]

    Properties

    Chemical formula

    		 C10H10Sn
    Molar mass 248.900 g·mol−1
    Structure[2]

    Crystal structure

    		 orthorhombic

    Space group

    		 Pbcm, No.57

    Lattice constant

    a = 5.835 Å, b = 25.385 Å, c = 12.785 Å

    Formula units (Z)

    		 8 formula per cell

    Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

    Infobox references

    Stannocene is an organometallic compound with the formula Sn(C5H5)2. It is a metallocene that can be produced efficiently from cyclopentadienyl sodium and tin(II) chloride.[3] Unlike in ferrocene the two cyclopentadienyl rings are not parallel.[4]

    References

    [edit]
    1. ^ Stannocene
  • ^ Atwood, Jerry L.; Hunter, William E; Cowley, Alan H.; Jones, Richard A.; Stewart, Constantine A. "X-Ray Crystal Structures of Bis(cyclopentadienyl)tin and Bis(pentamethylcyclopentadienyl)lead". J. Chem. Soc., Chem. Commun.
  • ^ Janiak, Christpher (2010), "Stannocene as cyclopentadienyl transfer agent in transmetallation reactions with lanthanide metals for the synthesis of tris(cyclopentadienyl)lanthanides", Zeitschrift für anorganische und allgemeine Chemie, 636 (13–14): 2387–2390, doi:10.1002/zaac.201000239
  • ^ Smith, P. J. (2012). Chemistry of Tin. Springer Science & Business Media. ISBN 9789401149389.
    • Stub icon

    This article about an organic compound is a stub. You can help Wikipedia by expanding it.

  • t
  • e

    • Retrieved from "https://en.wikipedia.org/w/index.php?title=Stannocene&oldid=1188732928"
    Categories: 
    ●Organotin compounds
     ●Metallocenes
     ●Tin(II) compounds
     ●Cyclopentadienyl complexes
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