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F r o m W i k i p e d i a , t h e f r e e e n c y c l o p e d i a
Tellurium tetrafluoride , TeF4 , is a stable, white, hygroscopic crystalline solid and is one of two fluorides of tellurium . The other binary fluoride is tellurium hexafluoride .[1] The widely reported Te 2 F 10 has been shown to be F5 TeOTeF5 [1] There are other tellurium compounds that contain fluorine, but only the two mentioned contain solely tellurium and fluorine. Tellurium difluoride, TeF2 , and ditellurium difluoride, Te2 F 2 are not known.[1]
Preparation
[ edit ]
Tellurium tetrafluoride can be prepared by the following reaction:
TeO2 + 2SF 4 → TeF4 + 2SOF2
It is also prepared by reacting nitryl fluoride with tellurium or from the elements at 0 °C or by reacting selenium tetrafluoride with tellurium dioxide at 80 °C.
Fluorine in nitrogen can react with TeCl2 or TeBr2 to form TeF4 . PbF2 will also fluorinate tellurium to TeF4 .
Reactivity
[ edit ]
Tellurium tetrafluoride will react with water or silica and forms tellurium oxides. Copper , silver , gold or nickel will react with tellurium tetrafluoride at 185 °C. It does not react with platinum . It is soluble in SbF5 and will precipitate out the complex TeF4 SbF5 .
Properties
[ edit ]
Te coordination
Tellurium tetrafluoride melts at 130 °C and decomposes to tellurium hexafluoride at 194 °C. In the solid phase, it consists of infinite chains of TeF3 F 2/2 in an octahedral geometry. A lone pair of electrons occupies the sixth position.
References
[ edit ]
R.B. King; Inorganic Chemistry of Main Group Elements , VCH Publishers, New York, 1995.
W.C. Cooper; Tellurium , VanNostrand Reinhold Company, New York, 1971.
t
e
PF 6 − , AsF6 − , SbF6 − compounds
AlF6 − compounds
chlorides, bromides, iodides and pseudohalogenides
SiF6 2- , GeF6 2- compounds
Oxyfluorides
Organofluorides
with transition metal, lanthanide, actinide, ammonium
nitric acids
bifluorides
thionyl, phosphoryl, and iodosyl
Chemical formulas
R e t r i e v e d f r o m " https://en.wikipedia.org/w/index.php?title=Tellurium_tetrafluoride&oldid=1100697476 "
C a t e g o r i e s :
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H i d d e n c a t e g o r i e s :
● A r t i c l e s w i t h o u t I n C h I s o u r c e
● C h e m i c a l p a g e s w i t h o u t C h e m S p i d e r I D
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● T h i s p a g e w a s l a s t e d i t e d o n 2 7 J u l y 2 0 2 2 , a t 0 6 : 4 8 ( U T C ) .
● T e x t i s a v a i l a b l e u n d e r t h e C r e a t i v e C o m m o n s A t t r i b u t i o n - S h a r e A l i k e L i c e n s e 4 . 0 ;
a d d i t i o n a l t e r m s m a y a p p l y . B y u s i n g t h i s s i t e , y o u a g r e e t o t h e T e r m s o f U s e a n d P r i v a c y P o l i c y . W i k i p e d i a ® i s a r e g i s t e r e d t r a d e m a r k o f t h e W i k i m e d i a F o u n d a t i o n , I n c . , a n o n - p r o f i t o r g a n i z a t i o n .
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