Names | |
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IUPAC name
Hafnium triiodide | |
Identifiers | |
3D model (JSmol) |
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PubChem CID |
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Properties | |
HfI3 | |
Molar mass | 559.20 g·mol−1 |
Appearance | black crystals[1] |
Melting point | decomposes |
Related compounds | |
Other anions |
Hafnium(III) chloride Hafnium(III) bromide |
Other cations |
Titanium(III) iodide Zirconium(III) iodide |
Related compounds |
Hafnium(IV) iodide |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Hafnium(III) iodide is an inorganic compoundofhafnium and iodine with the formula Hf I3. It is a black solid.[2]
Like other group 4 trihalides, hafnium(III) iodide can be prepared from hafnium(IV) iodide by high-temperature reduction with hafnium metal, although incomplete reaction and contamination of the product with excess metal often occurs.[2]
Other metals can be used as the reducing agent, for example aluminium. The product is often nonstoichiometric, with the compositions Hf I3.2–3.3 and Hf I3.0–3.5 reported.[3][4]
Hafnium(III) iodide adopts the same crystal structureaszirconium(III) iodide.[5] This is very similar to the β-TiCl3 structure.[2] The structure is based on hexagonal close packingofiodide ions with one third of the octahedral interstices occupied by Hf3+ ions.[2] It consists of parallel chains of face-sharing {HfI6} octahedra.[5]
Hafnium(III) iodide has a lower magnetic moment than is expected for the d1 metal ion Hf3+, indicating non-negligible Hf–Hf bonding.[2] The Hf–Hf separation was originally reported to be 3.295 Å,[6] but a subsequent study of nonstoichiometric hafnium(III) iodide indicated a lower symmetry structure.[3]
Like the chloride and bromide, hafnium(III) iodide is a powerful enough reducing agent to reduce water and therefore does not have any aqueous chemistry.[2]
Salts and covalent derivatives of the iodide ion
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