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F r o m W i k i p e d i a , t h e f r e e e n c y c l o p e d i a
Nuclides with atomic number of 18 but with different mass numbers
Argon (18 Ar ) has 26 known isotopes , from 29 Ar to 54 Ar, and one isomer (32m Ar ), of which three are stable (36 Ar, 38 Ar, and 40 Ar ). On the Earth, 40 Ar makes up 99.6% of natural argon. The longest-lived radioactive isotopes are 39 Ar with a half-life of 268 years, 42 Ar with a half-life of 32.9 years, and 37 Ar with a half-life of 35.04 days. All other isotopes have half-lives of less than two hours, and most less than one minute. The least stable is 29 Ar with a half-life of approximately 4 × 10 −20 seconds.[4]
The naturally occurring 40 K , with a half-life of 1.248× 10 9 years, decays to stable 40 Ar by electron capture (10.72%) and by positron emission (0.001%), and also transforms to stable 40 Ca via beta decay (89.28%). These properties and ratios are used to determine the age of rocks through potassium–argon dating .[5]
Despite the trapping of 40 Ar in many rocks, it can be released by melting, grinding, and diffusion. Almost all of the argon in the Earth's atmosphere is the product of 40 K decay, since 99.6% of Earth atmospheric argon is 40 Ar, whereas in the Sun and presumably in primordial star-forming clouds, argon consists of < 15% 38 Ar and mostly (85%) 36 Ar. Similarly, the ratio of the three isotopes 36 Ar:38 Ar:40 Ar in the atmospheres of the outer planets is measured to be 8400:1600:1.[6]
In the Earth's atmosphere , radioactive 39 Ar (half-life 268(8 ) years) is made by cosmic ray activity, primarily from 40 Ar. In the subsurface environment, it is also produced through neutron capture by 39 K or alpha emission by calcium . The content of 39 Ar in natural argon is measured to be of (8.0±0.6)×10−16 g/g, or (1.01±0.08) Bq/kg of 36, 38, 40 Ar.[7] The content of 42 Ar (half-life 33 years) in the Earth's atmosphere is lower than 6×10−21 parts per part of 36, 38, 40 Ar.[8] Many endeavors require argon depleted in the cosmogenic isotopes , known as depleted argon.[9] Lighter radioactive isotopes can decay to different elements (usually chlorine ) while heavier ones decay to potassium .
36 Ar, in the form of argon hydride , was detected in the Crab Nebula supernova remnant during 2013.[10] [11] This was the first time a noble molecule was detected in outer space .[10] [11]
37 Ar is a synthetic radionuclide that is created via neutron capture of 40 Ca followed by alpha particle emission, as a result of subsurface nuclear explosions . It has a half-life of 35 days.[5]
List of isotopes [ edit ]
Nuclide[12] [n 1]
Z
N
Isotopic mass (Da ) [13] [n 2] [n 3]
Half-life
Decay mode [n 4]
Daughter isotope [n 5]
Spin andparity [n 6] [n 7]
Natural abundance (mole fraction)
Excitation energy
Normal proportion
Range of variation
29 Ar [4]
18
11
~40 zs
2p
27 S
30 Ar
18
12
30.02247(22 )
<10 ps
2p
28 S
0+
31 Ar
18
13
31.01216(22 )#
15.1(3 ) ms
β+ , p (68.3%)
30 S
5/2+
β+ (22.63%)
31 Cl
β+ , 2p (9.0%)
29 P
β+ , 3p (0.07%)
28 Si
32 Ar
18
14
31.9976378(19 )
98(2 ) ms
β+ (64.42%)
32 Cl
0+
β+ , p (35.58%)
31 S
32m Ar
5600(100) keV
unknown
5−#
33 Ar
18
15
32.9899255(4 )
173.0(20 ) ms
β+ (61.3%)
33 Cl
1/2+
β+ , p (38.7%)
32 S
34 Ar
18
16
33.98027009(8 )
843.8(4 ) ms
β+
34 Cl
0+
35 Ar
18
17
34.9752577(7 )
1.7756(10 ) s
β+
35 Cl
3/2+
36 Ar
18
18
35.967545105(29 )
Observationally Stable [n 8]
0+
0.003336(4 )
37 Ar
18
19
36.96677631(22 )
35.011(19 ) d
EC
37 Cl
3/2+
Trace[n 9]
38 Ar
18
20
37.96273210(21 )
Stable
0+
0.000629(1 )
39 Ar [n 10]
18
21
38.964313(5 )
268.2+3.1 −2.9 y [14]
β−
39 K
7/2−
Trace[n 9]
40 Ar [n 11]
18
22
39.9623831238(24 )
Stable
0+
0.996035(4 )[n 12]
41 Ar
18
23
40.9645006(4 )
109.61(4 ) min
β−
41 K
7/2−
Trace[n 9]
42 Ar
18
24
41.963046(6 )
32.9(11 ) y
β−
42 K
0+
43 Ar
18
25
42.965636(6 )
5.37(6 ) min
β−
43 K
5/2(−)
44 Ar
18
26
43.9649238(17 )
11.87(5 ) min
β−
44 K
0+
45 Ar
18
27
44.9680397(6 )
21.48(15 ) s
β−
45 K
(5/2,7/2)−
46 Ar
18
28
45.9680374(12 )
8.4(6 ) s
β−
46 K
0+
47 Ar
18
29
46.9727681(12 )
1.23(3 ) s
β− (99.8%)
47 K
(3/2−)
β− , n (0.2%)
46 K
48 Ar
18
30
47.97608(33 )
415(15 ) ms
β−
48 K
0+
49 Ar
18
31
48.98155(43 )#
236(8 ) ms
β−
49 K
3/2−#
50 Ar
18
32
49.98569(54 )#
106(6 ) ms
β−
50 K
0+
51 Ar
18
33
50.99280(64 )#
60# ms [>200 ns ]
β−
51 K
3/2−#
52 Ar
18
34
51.99863(64 )#
10# ms
β−
52 K
0+
53 Ar
18
35
53.00729(75 )#
3# ms
β−
53 K
(5/2−)#
β− , n
52 K
54 Ar [15]
18
36
β−
54 K
0+
This table header & footer:
^ ( ) – Uncertainty (1 σ ) is given in concise form in parentheses after the corresponding last digits.
^ # – Atomic mass marked #: value and uncertainty derived not from purely experimental data, but at least partly from trends from the Mass Surface (TMS).
^
Modes of decay:
^ Bold symbol as daughter – Daughter product is stable.
^ ( ) spin value – Indicates spin with weak assignment arguments.
^ # – Values marked # are not purely derived from experimental data, but at least partly from trends of neighboring nuclides (TNN).
^ Believed to undergo double electron capture to 36 S (lightest theoretically unstable nuclide for which no evidence of radioactivity has been observed)
^ a b c Cosmogenic nuclide
^ Used in argon–argon dating
^ Used in argon–argon dating and potassium–argon dating
^ Generated from 40 K in rocks. These ratios are terrestrial. Cosmic abundance is far less than 36 Ar.
References [ edit ]
^ Prohaska, Thomas; Irrgeher, Johanna; Benefield, Jacqueline; Böhlke, John K.; Chesson, Lesley A.; Coplen, Tyler B.; Ding, Tiping; Dunn, Philip J. H.; Gröning, Manfred; Holden, Norman E.; Meijer, Harro A. J. (4 May 2022). "Standard atomic weights of the elements 2021 (IUPAC Technical Report)" . Pure and Applied Chemistry . doi :10.1515/pac-2019-0603 . ISSN 1365-3075 .
^ a b Mukha, I.; et al. (2018). "Deep excursion beyond the proton dripline. I. Argon and chlorine isotope chains". Physical Review C . 98 (6 ): 064308–1–064308–13. arXiv :1803.10951 . Bibcode :2018PhRvC..98f4308M . doi :10.1103/PhysRevC.98.064308 . S2CID 119384311 .
^ a b
"40 Ar/39 Ar dating and errors" . Archived from the original on 9 May 2007. Retrieved 7 March 2007 .
^ Cameron, A.G.W. (1973). "Elemental and isotopic abundances of the volatile elements in the outer planets". Space Science Reviews . 14 (3–4): 392–400. Bibcode :1973SSRv...14..392C . doi :10.1007/BF00214750 . S2CID 119861943 .
^
P. Benetti; et al. (2007). "Measurement of the specific activity of 39 Ar in natural argon". Nuclear Instruments and Methods A . 574 (1 ): 83–88. arXiv :astro-ph/0603131 . Bibcode :2007NIMPA.574...83B . doi :10.1016/j.nima.2007.01.106 . S2CID 17073444 .
^
V. D. Ashitkov; et al. (1998). "New experimental limit on the 42 Ar content in the Earth's atmosphere". Nuclear Instruments and Methods A . 416 (1 ): 179–181. Bibcode :1998NIMPA.416..179A . doi :10.1016/S0168-9002(98 )00740-2 .
^
H. O. Back; et al. (2012). "Depleted Argon from Underground Sources" . Physics Procedia . 37 : 1105–1112. Bibcode :2012PhPro..37.1105B . doi :10.1016/j.phpro.2012.04.099 .
^ a b Quenqua, Douglas (13 December 2013). "Noble Molecules Found in Space" . The New York Times . Retrieved 13 December 2013 .
^ a b
Barlow, M. J.; et al. (2013). "Detection of a Noble Gas Molecular Ion, 36 ArH+, in the Crab Nebula". Science . 342 (6164): 1343–1345. arXiv :1312.4843 . Bibcode :2013Sci...342.1343B . doi :10.1126/science.1243582 . PMID 24337290 . S2CID 37578581 .
^ Half-life, decay mode, nuclear spin, and isotopic composition is sourced in:Audi, G.; Kondev, F. G.; Wang, M.; Huang, W. J.; Naimi, S. (2017). "The NUBASE2016 evaluation of nuclear properties" (PDF) . Chinese Physics C . 41 (3 ): 030001. Bibcode :2017ChPhC..41c0001A . doi :10.1088/1674-1137/41/3/030001 .
^ Wang, M.; Audi, G.; Kondev, F. G.; Huang, W. J.; Naimi, S.; Xu, X. (2017). "The AME2016 atomic mass evaluation (II ). Tables, graphs, and references" (PDF) . Chinese Physics C . 41 (3 ): 030003-1–030003-442. doi :10.1088/1674-1137/41/3/030003 .
^ Golovko, Victor V. (15 October 2023). "Application of the most frequent value method for 39 Ar half-life determination". The European Physical Journal C . 83 (10 ). arXiv :2310.06867 . doi :10.1140/epjc/s10052-023-12113-6 . ISSN 1434-6052 .
^ Neufcourt, L.; Cao, Y.; Nazarewicz, W.; Olsen, E.; Viens, F. (2019). "Neutron drip line in the Ca region from Bayesian model averaging". Physical Review Letters . 122 (6 ): 062502–1–062502–6. arXiv :1901.07632 . Bibcode :2019PhRvL.122f2502N . doi :10.1103/PhysRevLett.122.062502 . PMID 30822058 . S2CID 73508148 .
External links [ edit ]
R e t r i e v e d f r o m " https://en.wikipedia.org/w/index.php?title=Isotopes_of_argon&oldid=1226643312 "
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