Jump to content
 







Main menu
   


Navigation  



Main page
Contents
Current events
Random article
About Wikipedia
Contact us
Donate
 




Contribute  



Help
Learn to edit
Community portal
Recent changes
Upload file
 








Search  

































Create account

Log in
 









Create account
 Log in
 




Pages for logged out editors learn more  



Contributions
Talk
 



















Contents

   



(Top)
 


1 Giant birefringence  





2 List  





3 References  














Iodate nitrate







Add links
 









Article
Talk
 

















Read
Edit
View history
 








Tools
   


Actions  



Read
Edit
View history
 




General  



What links here
Related changes
Upload file
Special pages
Permanent link
Page information
Cite this page
Get shortened URL
Download QR code
Wikidata item
 




Print/export  



Download as PDF
Printable version
 
















Appearance
   

 






From Wikipedia, the free encyclopedia
 


Iodate nitrates are mixed anion compounds that contain both iodate and nitrate anions.

Giant birefringence[edit]

Iodate nitrates can have high birefringence. The scandium salt has a giant birefringence of 0.348 at 546 nm. When discovered in 2021 it was a record high birefringence for oxyanion compounds, but it was exceeded by CeF2(SO4) just a month later with a value of 0.361[1] and sodium hydrogen squarate hydrate, NaHC4O4·H2O with a value of 0.52 at 1064 nm.[2] All of these are beaten by hexagonal boron nitride (h-BN) with birefringence of 0.7 in visible light.[3]

List[edit]

formula name formula

weight

system space group cell Å volume density comments ref
Al(IO3)2NO3•6H2O aluminium diiodate nitrate hexahydrate hexagonal P321 a=6.764 c=8.09 Z=1 [4]
KIO3•KNO3•2HIO3 dipotassium dihydrogen triiodate nitrate orthorhombic P212121 a=7.109 b=10.638 c=15.5 [5]
Sc(IO3)2(NO3) scandium diiodate nitrate 1370.31 trigonal R32 a=5.3536 c=23.567 Z=1 584.96 3.890 colourless; giant birefringence 0.348 at 546 nm; SHG 4.0×KDP; UV edge 298 nm; stable to 360°C [6]
In(IO3)2(NO3) indium diiodate nitrate 526.63 trigonal R32 a=5.2165 c=24.195, γ=120° Z=3 570.2 4.601 colourless [7]
[In(IO3)(OH)(H2O)](NO3) 386.75 monoclinic P21/n a=5.5756 b=16.410 c=7.734, β=109.95 Z=4 665.2 3.862 colourless [7]
La(IO3)2(NO3) lanthanum diiodate nitrate trigonal P3121 a=7.1002 c=38.177 Z=9 SHG 0.6 × KDP; band gap 4.23 eV [8]
Ce(IO3)2(NO3) cerium diiodate nitrate 551.93 trigonal P3121 a=7.0537 c=37.972 Z=9 1639.8 5.030 SHG 1 × KDP [9]
α-Th(IO3)2(NO3)(OH) triclinic P1 a=6.9581 b=7.2294 c=9.8989 α=68.896° β=88.759° γ=66.620° [10]
β-Th(IO3)2(NO3)(OH) orthorhombic Pbca a=7.1459 b=14.140 c=16.612 [10]

References[edit]

  1. ^ Wu, Chao; Wu, Tianhui; Jiang, Xingxing; Wang, Zujian; Sha, Hongyuan; Lin, Lin; Lin, Zheshuai; Huang, Zhipeng; Long, Xifa; Humphrey, Mark G.; Zhang, Chi (2021-03-24). "Large Second-Harmonic Response and Giant Birefringence of CeF 2 (SO 4 ) Induced by Highly Polarizable Polyhedra". Journal of the American Chemical Society. 143 (11): 4138–4142. doi:10.1021/jacs.1c00416. hdl:1885/251607. ISSN 0002-7863. PMID 33625206. S2CID 232039261.
  • ^ Zhang, Xiaodong; Cao, Dongxu; Yang, Daqing; Wang, Ying; Wu, Kui; Lee, Ming-Hsien; Zhang, Bingbing (2022-04-04). "Finding the First Squarates Nonlinear Optical Crystal NaHC 4 O 4 ·H 2 O with Strong Second Harmonic Generation and Giant Birefringence". ACS Materials Letters. 4 (4): 572–576. doi:10.1021/acsmaterialslett.2c00114. ISSN 2639-4979. S2CID 247352687.
  • ^ Segura, A.; Artús, L.; Cuscó, R.; Taniguchi, T.; Cassabois, G.; Gil, B. (6 February 2018). "Natural optical anisotropy of h-BN: Highest giant birefringence in a bulk crystal through the mid-infrared to ultraviolet range". Physical Review Materials. 2 (2): 024001. doi:10.1103/PhysRevMaterials.2.024001. hdl:10261/161209. S2CID 115229555.
  • ^ Cradwick, Peter D.; de Endredy, Andrew S. (1975). "Crystal structure of aluminium iodate nitrate hexahydrate". Journal of the Chemical Society, Dalton Transactions (19): 1926–1929. doi:10.1039/dt9750001926. ISSN 0300-9246.
  • ^ Kalinin, V.R.; Ilyukhin, V.V.; Belov, N.V. (1978). "Crystal structure of acid mixed potassium iodate-nitrate KIO3xKNO3x2HIO3". Doklady Akademii Nauk SSSR (in Russian). 239 (6).
  • ^ Wu, Chao; Jiang, Xingxing; Wang, Zujian; Lin, Lin; Lin, Zheshuai; Huang, Zhipeng; Long, Xifa; Humphrey, Mark G.; Zhang, Chi (2021-02-15). "Giant Optical Anisotropy in the UV‐Transparent 2D Nonlinear Optical Material Sc(IO 3 ) 2 (NO 3 )". Angewandte Chemie International Edition. 60 (7): 3464–3468. doi:10.1002/anie.202012456. hdl:1885/251539. ISSN 1433-7851. PMID 33146456. S2CID 226251002.
  • ^ a b Huang, Yu; Jiang, Ting-kun; Yang, Bing-Ping; Hu, Chun-Li; Fang, Zhi; Mao, Jiang-Gao (2022-02-14). "Two Indium Iodate–Nitrates with Large Birefringence Induced by Hybrid Anionic Functional Groups and Their Favorable Arrangements". Inorganic Chemistry. 61 (8): 3374–3378. doi:10.1021/acs.inorgchem.2c00079. ISSN 0020-1669. PMID 35156368. S2CID 246813531.
  • ^ Mao, Fei-Fei; Hu, Chun-Li; Li, Bing-Xuan; Mao, Jiang-Gao (2017-11-20). "Acentric La 3 (IO 3 ) 8 (OH) and La(IO 3 ) 2 (NO 3 ): Partial Substitution of Iodate Anions in La(IO 3 ) 3 by Hydroxide or Nitrate Anion". Inorganic Chemistry. 56 (22): 14357–14365. doi:10.1021/acs.inorgchem.7b02508. ISSN 0020-1669. PMID 29120615.
  • ^ Ma, Nan; Huang, Yu; Hu, Chun-Li; Zhang, Ming-Zhi; Li, Bing-Xuan; Mao, Jiang-Gao (2023-09-07). "Ce(IO 3 ) 3 F and Ce(IO 3 ) 2 (NO 3 ): Two Mixed-Anion Cerium Iodates with Good Nonlinear Optical and Birefringent Properties". Inorganic Chemistry. 62 (37): 15329–15333. doi:10.1021/acs.inorgchem.3c02651. ISSN 0020-1669. PMID 37677152. S2CID 261607422.
  • ^ a b Wang, Yaxing; Duan, Tao; Weng, Zhehui; Ling, Jie; Yin, Xuemiao; Chen, Lanhua; Sheng, Daopeng; Diwu, Juan; Chai, Zhifang; Liu, Ning; Wang, Shuao (2017-11-06). "Mild Periodic Acid Flux and Hydrothermal Methods for the Synthesis of Crystalline f-Element-Bearing Iodate Compounds". Inorganic Chemistry. 56 (21): 13041–13050. doi:10.1021/acs.inorgchem.7b01855. ISSN 0020-1669. PMID 28991439.


  • Retrieved from "https://en.wikipedia.org/w/index.php?title=Iodate_nitrate&oldid=1184059813"

    Categories: 
    Iodates
    Nitrates
    Hidden category: 
    CS1 Russian-language sources (ru)
     



    This page was last edited on 8 November 2023, at 02:42 (UTC).

    Text is available under the Creative Commons Attribution-ShareAlike License 4.0; additional terms may apply. By using this site, you agree to the Terms of Use and Privacy Policy. Wikipedia® is a registered trademark of the Wikimedia Foundation, Inc., a non-profit organization.



    Privacy policy

    About Wikipedia

    Disclaimers

    Contact Wikipedia

    Code of Conduct

    Developers

    Statistics

    Cookie statement

    Mobile view



    Wikimedia Foundation
    Powered by MediaWiki