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Contents

   



(Top)
 


1 Synthesis  





2 Physical properties  





3 Uses and reactions  





4 References  














Osmium(III) chloride






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From Wikipedia, the free encyclopedia
 


Osmium(III) chloride
Names
Other names

trichloroosmium, osmium trichloride

Identifiers

CAS Number

  • 14996-60-2 trihydrate
  • 3D model (JSmol)

    ChemSpider
    ECHA InfoCard 100.033.247 Edit this at Wikidata
    EC Number
    • 236-587-7

    PubChem CID

    CompTox Dashboard (EPA)

    • InChI=1S/3ClH.Os/h3*1H;/q;;;+3/p-3

      Key: UAIHPMFLFVHDIN-UHFFFAOYSA-K

    • Cl[Os](Cl)Cl

    Properties

    Chemical formula

    Cl3Os
    Molar mass 296.58 g·mol−1
    Appearance black-brown crystals
    Melting point 560 °C (1,040 °F; 833 K)

    Solubility in water

    soluble

    Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

    Infobox references

    Osmium(III) chloride is an inorganic chemical compound of osmium metal and chlorine with the chemical formula OsCl3.[1][2]

    Synthesis[edit]

    Osmium(III) chloride can be made by a reaction of chlorine with osmium:

    2Os + 3Cl2 → 2OsCl3

    It can also be made by heating of osmium(IV) chloride:

    2OsCl4 → 2OsCl3 +Cl2

    Physical properties[edit]

    Sample of commercial osmium trichloride trihydrate.

    Osmium(III) chloride forms black-brown crystals.[3]

    Osmium(III) chloride forms a hydrate of the composition OsCl3·3H2O with dark green crystals.[4]

    Uses and reactions[edit]

    Osmium(III) chloride hydrate is used as a precursor material for the production of dichlorodihydridoosmium complex compounds and other compounds.[5]

    It is the precursor to a variety of arene complexes.[6]

    References[edit]

    1. ^ "Osmium(III) chloride". Sigma Aldrich. Retrieved 31 March 2023.
  • ^ Lide, David R. (19 June 2003). 1998 Freshman Achievement Award. CRC Press. p. 4-79. ISBN 978-0-8493-0594-8. Retrieved 31 March 2023.
  • ^ "Osmium(III) chloride". heraeus.com. Retrieved 31 March 2023.
  • ^ "Osmium(III) chloride hydrate, Thermo Scientific Chemicals | Fisher Scientific". fishersci.se. Retrieved 31 March 2023.
  • ^ "Osmium(III) chloride hydrate". Sigma Aldrich. Retrieved 31 March 2023.
  • ^ Bell, Andrew G.; Koźmiński, Wiktor; Linden, Anthony; von Philipsborn, Wolfgang (1996). "187Os NMR Study of (η6-Arene)osmium(II) Complexes: Separation of Electronic and Steric Ligand Effects". Organometallics. 15 (14): 3124–3135. doi:10.1021/om960053i.

  • Retrieved from "https://en.wikipedia.org/w/index.php?title=Osmium(III)_chloride&oldid=1192478935"

    Categories: 
    Osmium compounds
    Chlorides
    Metal halides
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    This page was last edited on 29 December 2023, at 16:14 (UTC).

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