Jump to content
 







Main menu
   


Navigation  



Main page
Contents
Current events
Random article
About Wikipedia
Contact us
Donate
 




Contribute  



Help
Learn to edit
Community portal
Recent changes
Upload file
 








Search  

































Create account

Log in
 









Create account
 Log in
 




Pages for logged out editors learn more  



Contributions
Talk
 



















Contents

   



(Top)
 


1 Structure  





2 Synthesis  





3 References  














Curium(III) chloride






Deutsch
Esperanto
Bahasa Indonesia
Русский
ி

 

Edit links
 









Article
Talk
 

















Read
Edit
View history
 








Tools
   


Actions  



Read
Edit
View history
 




General  



What links here
Related changes
Upload file
Special pages
Permanent link
Page information
Cite this page
Get shortened URL
Download QR code
Wikidata item
 




Print/export  



Download as PDF
Printable version
 
















Appearance
   

 






From Wikipedia, the free encyclopedia
 


Curium(III) chloride

Crystal structure

Identifiers

CAS Number

3D model (JSmol)

PubChem CID

  • InChI=1S/3ClH.Cm/h3*1H;/q;;;+3/p-3

    Key: PTLGMSBPLOHNBD-UHFFFAOYSA-K

  • Cl[Cm](Cl)Cl

Properties

Chemical formula

Cl3Cm
Molar mass 353 g·mol−1
Appearance White solid (anhydrous)
Light green solid (hydrate)
Melting point 695 °C (1,283 °F; 968 K)[citation needed]

Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Infobox references

Curium(III) chloride is the chemical compound with the formula CmCl3.

Structure

[edit]

Curium(III) chloride has a 9 coordinate tricapped trigonal prismatic geometry.[1]

Synthesis

[edit]

Curium(III) chloride can be obtained from the reaction of hydrogen chloride gas with curium dioxide, curium(III) oxide, or curium(III) oxychloride at a temperature of 400-600 °C:

CmOCl + 2HCl → CmCl3 + H2O

It can also be obtained from the dissolution of metallic curium in dilute hydrochloric acid:[2]

2Cm + 6HCl → 2CmCl3 + 3H2

This method has a number of disadvantages associated with the ongoing processes of hydrolysis and hydration of the resulting compound in an aqueous solution, making it problematic to obtain a pure product using this reaction.

It can be obtained from the reaction of curium nitride with cadmium chloride:[3]

2 CmN + 3 CdCl2 → 2 CmCl3 + Cd3N2

References

[edit]
  1. ^ Greenwood, N. N.; Earnshaw, A. (1997). Chemistry of the Elements (2nd ed.). Butterworth, UK. p. 1270.{{cite book}}: CS1 maint: location missing publisher (link)
  • ^ Wallmann, J. C.; Fuger, J.; Peterson, J. R.; Green, J. L. (1 November 1967). "Crystal structure and lattice parameters of curium trichloride". Journal of Inorganic and Nuclear Chemistry. 29 (11): 2745–2751. doi:10.1016/0022-1902(67)80013-7. ISSN 0022-1902. S2CID 97334114. Retrieved 3 July 2023.
  • ^ Hayashi, Hirokazu; Takano, Masahide; Otobe, Haruyoshi; Koyama, Tadafumi (July 2013). "Syntheses and thermal analyses of curium trichloride". Journal of Radioanalytical and Nuclear Chemistry. 297 (1): 139–144. doi:10.1007/s10967-012-2413-7. S2CID 95792512.

  • t
  • e
  • t
  • e

  • Retrieved from "https://en.wikipedia.org/w/index.php?title=Curium(III)_chloride&oldid=1212433472"

    Categories: 
    Curium compounds
    Nuclear materials
    Chlorides
    Actinide halides
    Nuclear technology stubs
    Inorganic compound stubs
    Hidden categories: 
    CS1 maint: location missing publisher
    Chemical pages without ChemSpiderID
    Articles without EBI source
    Articles without KEGG source
    Articles without UNII source
    All articles with unsourced statements
    Articles with unsourced statements from January 2022
    Articles containing unverified chemical infoboxes
    Articles with short description
    Short description matches Wikidata
    All stub articles
     



    This page was last edited on 7 March 2024, at 21:31 (UTC).

    Text is available under the Creative Commons Attribution-ShareAlike License 4.0; additional terms may apply. By using this site, you agree to the Terms of Use and Privacy Policy. Wikipedia® is a registered trademark of the Wikimedia Foundation, Inc., a non-profit organization.



    Privacy policy

    About Wikipedia

    Disclaimers

    Contact Wikipedia

    Code of Conduct

    Developers

    Statistics

    Cookie statement

    Mobile view



    Wikimedia Foundation
    Powered by MediaWiki