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Contents

   



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1 Physical properties  





2 References  














Californium(III) fluoride






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From Wikipedia, the free encyclopedia
 

(Redirected from Californium trifluoride)

Californium(III) fluoride
Names
Other names

Californium trifluoride

Identifiers

CAS Number

3D model (JSmol)

  • InChI=1S/Cf.3FH/h;3*1H/q+3;;;/p-3

    Key: RFYJBQZVUMTFMQ-UHFFFAOYSA-K

  • [Cf+3].[F-].[F-].[F-]

Properties

Chemical formula

CfF3
Molar mass 308 g·mol−1
Appearance yellow-green solid
Density g/cm3
Structure

Crystal structure

orthorhombic
Related compounds

Related compounds

Berkelium trifluoride
Einsteinium trifluoride
Hazards
Occupational safety and health (OHS/OSH):

Main hazards

radioactive

Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Infobox references

Californium(III) fluoride is a binary inorganic compoundofcalifornium and fluorine with the formula CfF
3
[1]

Physical properties[edit]

Californium(III) fluoride is a yellow-green solid[2] and has two crystalline structures that are temperature dependent. At low temperatures the orthorhombic structure (YF
3
type) is found with lattice constants a = 665.3(3) pm, b = 703.9(1) pm and c = 439.3(3) pm. At higher temperatures it forms a trigonal system (LaF
3
type) with: a = 694.5(3) pm and c = 710.1(2) pm. Here, each californium atom is surrounded by nine fluorine atoms in a distorted triply-capped trigonal-prismatic structure.[3][4]

References[edit]

  1. ^ Haupt, Axel (22 March 2021). Organic and Inorganic Fluorine Chemistry: Methods and Applications. Walter de Gruyter GmbH & Co KG. p. 618. ISBN 978-3-11-065933-7. Retrieved 6 April 2023.
  • ^ "WebElements Periodic Table » Californium » californium trifluoride". webelements.com. Retrieved 6 April 2023.
  • ^ Stevenson, J. N.; Peterson, J. R. (1 October 1973). "The trigonal and orthorhombic crystal structures of CfF3 and their temperature relationship". Journal of Inorganic and Nuclear Chemistry. 35 (10): 3481–3486. doi:10.1016/0022-1902(73)80356-2. ISSN 0022-1902. Retrieved 6 April 2023.
  • ^ Macintyre, Jane E. (23 July 1992). Dictionary of Inorganic Compounds. CRC Press. p. 2825. ISBN 978-0-412-30120-9. Retrieved 6 April 2023.

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    This page was last edited on 21 December 2023, at 13:05 (UTC).

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