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1 See also  





2 References  














Protactinium(V) chloride






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From Wikipedia, the free encyclopedia
 

(Redirected from Protactinium pentachloride)

Protactinium(V) chloride
Names
IUPAC name

Protactinium(V) chloride

Other names

Protactinium pentachloride, Protactinium chloride

Identifiers

CAS Number

3D model (JSmol)

ChemSpider

PubChem CID

CompTox Dashboard (EPA)

  • InChI=1S/5ClH.Pa/h5*1H;/q;;;;;+5/p-5

    Key: QRPCDPJECLHYKR-UHFFFAOYSA-I

  • Cl[Pa](Cl)(Cl)(Cl)Cl

Properties

Chemical formula

PaCl5
Molar mass 408.301 g/mol
Appearance yellow monoclinic crystals[1]
Density 3.74 g/cm3[1]
Melting point 306 °C (583 °F; 579 K)[1]
Boiling point 420 °C (788 °F; 693 K)[2]
Structure

Crystal structure

monoclinic, mS24

Space group

c12/c1, #15

Coordination geometry

Pa, 7, pentagonal bipyramidal
Cl, 1 and 2
Related compounds

Other anions

Protactinium(V) fluoride
Protactinium(V) bromide
Protactinium(V) iodide

Other cations

Praseodymium(III) chloride
Uranium(IV) chloride
Thorium(IV) chloride

Related compounds

Protactinium(IV) chloride

Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Infobox references

Protactinium(V) chloride is the chemical compound composed of protactinium and chlorine with the formula PaCl5. It forms yellow monoclinic crystals and has a unique structure composed of chains of 7 coordinate, pentagonal bipyramidal, protactinium atoms sharing edges.[3]

Protactinium(V) chloride can react with boron tribromide at high temperatures to form protactinium(V) bromide.[4] It also reacts with fluorine to form protactinium(V) fluoride at high temperatures.[4]

See also[edit]

References[edit]

  1. ^ a b c Lide, David R. (1998). Handbook of Chemistry and Physics (87 ed.). Boca Raton, FL: CRC Press. p. 484. ISBN 0849305942. Retrieved 2008-07-17.
  • ^ "Chemistry: WebElements Periodic Table: Professional Edition: Protactinium: compound data (protactinium (V) chloride)". WebElements. Retrieved 2008-07-17.[permanent dead link]
  • ^ R. P. Dodge, G. S. Smith, Q. Johnson, R. E. Elson: „The Crystal Structure of Protactinium Pentachloride“, Acta Crystallogr., 1967, 22, 85–89; doi:10.1107/S0365110X67000155.
  • ^ a b Georg Brauer (Hrsg.), unter Mitarbeit von Marianne Baudler u. a.: Handbuch der Präparativen Anorganischen Chemie. 3., umgearbeitete Auflage. Band I, Ferdinand Enke, Stuttgart 1975, ISBN 3-432-02328-6, S. 1177.

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