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1 References  














Carbon monosulfide






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From Wikipedia, the free encyclopedia
 


Carbon monosulfide
Lewis structure, showing a C–S bond distance of 1.5349 angstroms
Space-filling model of the carbon monosulfide molecule
Names
IUPAC name

carbon monosulfide

Other names

carbon(II) sulfide, thiocarbonyl, sulfidocarbon, methanidylidynesulfanium

Identifiers

CAS Number

3D model (JSmol)

Beilstein Reference

1697516, 1918616
ChEBI
ChemSpider

Gmelin Reference

648

PubChem CID

CompTox Dashboard (EPA)

  • InChI=1S/CS/c1-2 ☒N

    Key: DXHPZXWIPWDXHJ-UHFFFAOYSA-N ☒N

  • InChI=1/CS/c1-2

    Key: DXHPZXWIPWDXHJ-UHFFFAOYAW

  • [S+]#[C-]

Properties

Chemical formula

CS
Molar mass 44.07 g·mol−1
Appearance reddish crystalline powder

Solubility in water

insoluble
Related compounds

Other anions

Carbon monoxide

Other cations

Silicon monosulfide
Germanium monosulfide
Tin(II) sulfide
Lead(II) sulfide

Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

☒N verify (what is checkY☒N ?)

Infobox references

Carbon monosulfide is a chemical compound with the formula CS. This diatomic molecule is the sulfur analogue of carbon monoxide, and is unstable as a solid or a liquid, but it has been observed as a gas both in the laboratory and in the interstellar medium.[1] The molecule resembles carbon monoxide with a triple bond between carbon and sulfur. The molecule is not intrinsically unstable, but it tends to polymerize. This tendency reflects the greater stability of C–S single bonds.

Polymers with the formula (CS)n have been reported,[2] and the formal dimer is ethenedithione. Also, CS has been observed as a ligand in some transition metal complexes.

References[edit]

  1. ^ Wilson, R. W.; Penzias, A. A.; Wannier, P. G.; Linke, R. A. (1976). "Isotopic abundances in interstellar carbon monosulfide". Astrophysical Journal. 204 (pt 2): L135–L137. Bibcode:1976ApJ...204L.135W. doi:10.1086/182072.
  • ^ Chou, J.-H.; Rauchfuss, T. B. (1997). "Solvatothermal Routes to Poly(Carbon Monosulfide)s Using Kinetically Stabilized Precursors" (PDF). Journal of the American Chemical Society. 119 (19): 4537–4538. doi:10.1021/ja970042w.

  • Retrieved from "https://en.wikipedia.org/w/index.php?title=Carbon_monosulfide&oldid=1190632518"

    Categories: 
    Inorganic carbon compounds
    Monosulfides
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    This page was last edited on 19 December 2023, at 00:53 (UTC).

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