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Contents

   



(Top)
 


1 Synthesis  





2 Physical properties  





3 Chemical properties  





4 References  














Berkelium tetrafluoride






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From Wikipedia, the free encyclopedia
 

(Redirected from Berkelium(IV) fluoride)

Berkelium tetrafluoride
Names
Other names

berkelium(IV) fluoride

Identifiers

CAS Number

3D model (JSmol)

  • InChI=1S/Bk.4FH/h;4*1H/q+4;;;;/p-4

    Key: RCTCKHUWZHELJP-UHFFFAOYSA-J

  • [Bk+4].[F-].[F-].[F-].[F-]

Properties

Chemical formula

BkF4
Molar mass 323 g·mol−1
Appearance yellow-green solid

Solubility in water

practically insoluble
Structure

Crystal structure

monoclinic
Related compounds

Related compounds

Curium(III) fluoride, berkelium trifluoride

Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Infobox references

Berkelium tetrafluoride is a binary inorganic compoundofberkelium and fluorine with the chemical formula BkF4.[1]

Synthesis[edit]

Berkelium tetrafluoride may be formed by the fluorination of berkelium trioxide, dioxide, or trifluoride with elemental fluorine at elevated temperatures:

2Bk2O3 + 8F2 → 4BkF4 + 3O2
2BkF3 + F2 → 2BkF4

Physical properties[edit]

Berkelium(IV) fluoride forms light brown crystals of monoclinic crystal structure of uranium tetrafluoride type. Cell parameters: a = 1.2396 nm, b = 1.0466 nm, c = 0.8118 nm, angle β = 126.33°.[2][3]

Chemical properties[edit]

Berkelium tetrafluoride is reduced by lithium at elevated temperatures to metallic berkelium:[4]

BkF4 + 4Li → Bk + 4LiF

References[edit]

  1. ^ Cunningham, B. B. (January 1959). "Berkelium and californium". Journal of Chemical Education. 36 (1): 32. doi:10.1021/ed036p32. ISSN 0021-9584. Retrieved 5 April 2023.
  • ^ Keenan, Thomas K.; Asprey, Larned B. (February 1969). "Lattice constants of actinide tetrafluorides including berkelium". Inorganic Chemistry. 8 (2): 235–238. doi:10.1021/ic50072a011. ISSN 0020-1669. Retrieved 5 April 2023.
  • ^ Asprey, L. B.; Keenan, T. K. (1 September 1968). "The preparation of berkelium tetrafluoride and its lattice parameters (1)". Inorganic and Nuclear Chemistry Letters. 4 (9): 537–541. doi:10.1016/0020-1650(68)80028-5. ISSN 0020-1650. Retrieved 5 April 2023.
  • ^ Edelstein, Norman M. (11 September 2013). Actinides in Perspective: Proceedings of the Actinides—1981 Conference, Pacific Grove, California, USA, 10-15 September 1981. Elsevier. p. 334. ISBN 978-1-4831-9051-8. Retrieved 5 April 2023.

  • Retrieved from "https://en.wikipedia.org/w/index.php?title=Berkelium_tetrafluoride&oldid=1192691467"

    Categories: 
    Fluorides
    Berkelium compounds
    Actinide halides
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    This page was last edited on 30 December 2023, at 20:33 (UTC).

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